Skip to main content
SpringerLink
Log in

Energy Characteristics of a Strontium Monohydroxide Molecule

  • STRUCTURE OF MATTER AND QUANTUM CHEMISTRY
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

A full set of the energy characteristics describing dissociation (Do(Sr–OH) = 401.8 ± 3.0 kJ/mol), ionization (Io(SrOH) = 5.372 ± 0.042 eV), and radiation power in the visible spectrum where the brightest bands with momenta Re (au) of transitions A2Π → X2Σ (2.08 ± 0.15) and B2Σ → X2Σ (1.79 ± 0.13) are located is determined for strontium monohydroxide via spectrophotometry, and from a physical model.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

Notes

  1. The error in C corresponds to the uncertainty in q.

  2. Value a = 1.1 was given for T = 2500 K in [21]. It was recalculated to the temperature of the flames of ∼2700 K used here, at which self-absorption was highest but still no more than 20%.

REFERENCES

  1. V. N. Belyaev, Russ. J. Phys. Chem. A 90, 2188 (2016).

    Article  CAS  Google Scholar 

  2. V. N. Belyaev and N. L. Lebedeva, Russ. J. Phys. Chem. A 86, 920 (2012).

    Article  CAS  Google Scholar 

  3. V. N. Belyaev and N. L. Lebedeva, Russ. J. Phys. Chem. A 84, 1841 (2010).

    Article  CAS  Google Scholar 

  4. V. N. Belyaev, N. L. Lebedeva, and K. S. Krasnov, Russ. J. Phys. Chem. A 70, 1328 (1996).

    Google Scholar 

  5. L. V. Gurvich, I. V. Veits, V. A. Medvedev, et al., Thermodynamic Properties of Individual Substances, The Reference Book, Ed. by V. P. Glushko (Nauka, Moscow, 1978–1982), Vols. 1–4 [in Russian].

  6. Yu. N. Dmitriev, Cand. Sci. (Phys. Math.) Dissertation (Inst. High Temp. Acad. Sci. SSSR, Moscow, 1988).

  7. P. D. Kleinschmidt, K. H. Lau, and D. L. Hildenbrand, J. Chem. Phys. 74, 653 (1981).

    Article  CAS  Google Scholar 

  8. L. V. Gurvich, V. G. Ryabova, A. N. Khitrov, and E. M. Starovoitov, Teplofiz. Vys. Temp. 9, 290 (1971).

    CAS  Google Scholar 

  9. L. V. Gurvich, V. G. Ryabova, and A. N. Khitrov, Faraday Symp. Chem. Soc., No. 8, 83 (1973).

  10. A. N. Khitrov, Cand. Sci. (Chem.) Dissertation (Inst. High Temp. Acad. Sci. SSSR, Moscow, 1974).

  11. D. E. Jensen and G. A. Jones, Proc. R. Soc. London, Ser. A 364, 509 (1978).

    Article  CAS  Google Scholar 

  12. E. Murad, J. Chem. Phys. 75, 4080 (1981).

    Article  CAS  Google Scholar 

  13. J. van der Hurk, Tj. Hollander, and C. Th. J. Alkemade, J. Quant. Spectr. Radiat. Transfer 13, 273 (1973).

    Article  CAS  Google Scholar 

  14. E. M. Bulewicz, C. G. James, and T. M. Sugden, Proc. R. Soc. London, Ser. A 235, 89 (1956).

    Article  CAS  Google Scholar 

  15. M. W. Chase, Jr., J. L. Curnutt, R. A. McDonald, and A. N. Syverud, J. Phys. Chem. Ref. Data 7 (3), 793 (1978).

  16. J. Nakagawa, R. F. Wormsbecher, and D. O. Harris, J. Mol. Spectrosc. 97, 37 (1983).

    Article  CAS  Google Scholar 

  17. C. R. Brazier and P. F. Bernath, J. Mol. Spectrosc. 114, 163 (1985).

    Article  CAS  Google Scholar 

  18. V. N. Belyaev, N. L. Lebedeva, K. S. Krasnov, and L. V. Gurvich, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 25, 834 (1982).

    CAS  Google Scholar 

  19. P. J. Dagdigian, H. W. Cruse, and R. N. Zare, J. Chem. Phys. 60, 2330 (1974).

    Article  CAS  Google Scholar 

  20. N. L. Lebedeva and V. N. Belyaev, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 36 (6), 27 (1993).

    CAS  Google Scholar 

  21. E. Hinnov and H. Kohn, J. Opt. Soc. Am. 47, 156 (1957).

    Article  CAS  Google Scholar 

  22. N. J. Friswell and D. R. Jenkins, Combust. Flame 19, 197 (1972).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    V. N. Belyaev

Authors
  1. V. N. Belyaev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. N. Belyaev.

Additional information

Translated by E. Boltukhina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Belyaev, V.N. Energy Characteristics of a Strontium Monohydroxide Molecule. Russ. J. Phys. Chem. 93, 2203–2212 (2019). https://doi.org/10.1134/S0036024419110062

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024419110062

Keywords:

Search

Navigation