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Hydrogenation of Acetophenone at Room Temperature and Atmospheric Pressure over Pt-Containing Catalysts Supported on Reducible Oxides

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Abstract

Complete conversion of acetophenone is achieved over 1% Pt/CеО2–ZrО2 catalyst in 2 h at room temperature and atmospheric pressure. Catalysts supported on the synthesized cerium–zirconium carriers show abnormally high hydrogen absorption in the temperature range of −50 to +25°С, and significantly exceed the activity of commercial samples in acetophenone hydrogenation.

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ACKNOWLEDGMENTS

This work was supported by the Russian Science Foundation, project no. 17-73-20282. The authors are grateful to I.V. Mishin for XRD studies, and the Department of Structural Studies of Zelinsky Institute of Organic Chemistry for electron microscopy characterization.

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Authors and Affiliations

  1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    K. V. Vikanova, E. A. Redina, G. I. Kapustin, N. A. Davshan & L. M. Kustov

  2. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    L. M. Kustov

Authors
  1. K. V. Vikanova
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  2. E. A. Redina
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  3. G. I. Kapustin
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  4. N. A. Davshan
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  5. L. M. Kustov
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Correspondence to K. V. Vikanova.

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Translated by L. Brovko

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Vikanova, K.V., Redina, E.A., Kapustin, G.I. et al. Hydrogenation of Acetophenone at Room Temperature and Atmospheric Pressure over Pt-Containing Catalysts Supported on Reducible Oxides. Russ. J. Phys. Chem. 93, 231–235 (2019). https://doi.org/10.1134/S003602441901031X

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  • DOI: https://doi.org/10.1134/S003602441901031X

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