Abstract
The effect hydrocarbonates and chlorides, the most common anions in natural and waste waters, on the oxidation of bisphenol A by persulfate activated with iron ions and simulated solar radiation is studied. It is established that hydrocarbonates have an inhibiting effect due to deactivation of Fe2+ ions and non-target expenditure of the in situ generated reactive oxygen species by reactions with hydrocarbonates. It is found that chlorides have a promoting effect: the reaction of bisphenol A oxidation is accelerated by 1.25–1.4 times, and the degree of mineralization grows by 18–44%. The established patterns are in good agreement with the existing data for real aqueous systems (surface waters of lakes Baikal and Gusinoe).
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ACKNOWLEDGMENTS
This work was performed as part of State Task no. 0339-2016-0005 for the Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences.
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Khandarkhaeva, M.S., Munkoeva, V.A., Batoeva, A.A. et al. Effect of Hydrocarbonates and Chlorides on the Photodestruction of Bisphenol A. Russ. J. Phys. Chem. 92, 2570–2574 (2018). https://doi.org/10.1134/S0036024418120208
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DOI: https://doi.org/10.1134/S0036024418120208