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Formation of Molybdenum Blue Particles via the Reduction of a Molybdate Solution with Glucose

  • PHYSICAL CHEMISTRY OF NANOCLUSTERS AND NANOMATERIALS
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Abstract

Molybdenum blue dispersions are synthesized via the reduction of molybdate with glucose in an acidic medium. Spectrophotometry and photon correlation spectroscopy show that, depending on the reducing agent/molybdate ratio and the pH value, both colored complex Mo compounds and dispersed phase particles (large molybdenum oxide clusters) can form. It is shown that particles form in the 1.4–2.2 range of the dispersion medium’s pH and ceases 21 days after synthesis (at room temperature).

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REFERENCES

  1. A. Müller, J. Meyer, E. Krickemeyer, and E. Diemann, Angew. Chem., Int. Ed. Engl. 35, 1206 (1996).

    Article  Google Scholar 

  2. A. Müller, E. Diemann, C. Kuhlmann, et al., Chem. Commun. 4, 1928 (2001).

    Article  CAS  Google Scholar 

  3. T. Liu, E. Diemann, and A. Muller, J. Chem. Educat. 84, 526 (2007).

    Article  CAS  Google Scholar 

  4. E. A. Nagul, I. D. McKelvie, P. Worsfold, and S. D. Kolev, Anal. Chim. Acta 890, 60 (2015).

    Article  CAS  PubMed  Google Scholar 

  5. A. A. Ostroushko and M. O. Tonkushina, Russ. J. Phys. Chem. A 90, 436 (2016).

    Article  CAS  Google Scholar 

  6. D. L. Long, E. Burkholder, and L. Cronin, Chem. Soc. Rev., No. 36, 105 (2007).

  7. H. N. Miras, E. F. Wilson, and L. Cronin, Chem. Commun. 11, 1297 (2009).

    Article  CAS  Google Scholar 

  8. I. Nakamura and H. Miras, J. Am. Chem. Soc. 137, 6524 (2015).

    Article  CAS  PubMed  Google Scholar 

  9. S. S. Talismanov and I. L. Eremenko, Russ. Chem. Rev. 72, 555 (2003).

    Article  CAS  Google Scholar 

  10. M. D. Bazhenova, N. N. Gavrilova, and V. V. Nazarov, Colloid. J. 77, 1 (2015).

    Article  CAS  Google Scholar 

  11. K. I. Popov, N. M. Sultanova, and H. Rönkkömäki, Russ. J. Phys. Chem. A 80, 1680 (2006).

    Article  CAS  Google Scholar 

  12. A. I. Busev, Analytical Chemistry of Molybdenum (Akad. Nauk SSSR, Moscow, 1962) [in Russian].

    Google Scholar 

  13. J. Liu, G. Qin, and Y. Ikushima, Chem.–Eur. J. 12, 2131 (2006).

    Article  PubMed  Google Scholar 

  14. A. A. Ostroushko, V. Yu. Korotaev, M. O. Tonkushina, K. V. Grzhegorzhevskii, V. A. Vazhenin, I. B. Kutyashev, N. A. Martynova, S. Yu. Men’shikov, and N. V. Selezneva, Russ. J. Phys. Chem. A 86, 1268 (2012).

    Article  CAS  Google Scholar 

  15. A. A. Ostroushko and M. O. Tonkushina, Russ. J. Phys. Chem. A 89, 443 (2015).

    Article  CAS  Google Scholar 

  16. M. V. Mokhosoev, State of Molybdenum and Tungsten Ions in Aqueous Solutions (Buryatsk. Knizhn. Izdat., Ulan-Ude, 1977) [in Russian].

    Google Scholar 

  17. H. N. Miras, C. J. Richmond, D.-L. Long, and L. Cronin, J. Am. Chem. Soc. 134, 3816 (2012).

    Article  CAS  PubMed  Google Scholar 

  18. V. A. Nazarenko, V. P. Antonovich, and E. M. Nevskaya, The Hydrolysis of Metal Ions in Diluted Solutions (Atomizdat, Moscow, 1979) [in Russian].

    Google Scholar 

  19. A. Müller and C. Serain, Acc. Chem. Res. 33, 2 (2000).

    Article  CAS  PubMed  Google Scholar 

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology, 125047, Moscow, Russia

    M. A. Myachina, N. N. Gavrilova & V. V. Nazarov

Authors
  1. M. A. Myachina
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  2. N. N. Gavrilova
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  3. V. V. Nazarov
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Correspondence to M. A. Myachina.

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Translated by M. Timoshinina

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Myachina, M.A., Gavrilova, N.N. & Nazarov, V.V. Formation of Molybdenum Blue Particles via the Reduction of a Molybdate Solution with Glucose. Russ. J. Phys. Chem. 92, 2237–2241 (2018). https://doi.org/10.1134/S0036024418110298

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  • DOI: https://doi.org/10.1134/S0036024418110298

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