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Ion-Exchange Sorption of Palladium(II) from Hydrochloric Acid Solutions in the Presence of Silver(I)

  • PHYSICAL CHEMISTRY OF SEPARATION PROCESSES. CHROMATOGRAPHY
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Abstract

The sorptive extraction of palladium(II) chloride complexes in the presence of silver(I) chloride complexes from 2 and 4 M aqueous solutions of HCl with a series of Purolite anionites with different functional groups is studied. An anion exchange mechanism of sorption is identified from Raman spectroscopy data. Kinetic properties that are inherent to the investigated ionites and allow the elution of palladium(II) and silver(I) after their extraction in a dynamic mode are revealed.

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ACKNOWLEDGMENTS

The authors are grateful to the Moscow representative office of Purolite Ltd., and to M.A. Mikhailenko personally, for supplying the ionite samples for our investigations.

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Authors and Affiliations

  1. Institute of Nonferrous Metals and Materials Science, Siberian Federal University, 660025, Krasnoyarsk, Russia

    O. N. Kononova, E. V. Duba & D. V. Medovikov

  2. Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036, Krasnoyarsk, Russia

    A. S. Krylov

Authors
  1. O. N. Kononova
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  2. E. V. Duba
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  3. D. V. Medovikov
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  4. A. S. Krylov
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Correspondence to O. N. Kononova.

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Translated by O. Polyakov

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Kononova, O.N., Duba, E.V., Medovikov, D.V. et al. Ion-Exchange Sorption of Palladium(II) from Hydrochloric Acid Solutions in the Presence of Silver(I). Russ. J. Phys. Chem. 92, 2053–2059 (2018). https://doi.org/10.1134/S0036024418100138

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  • DOI: https://doi.org/10.1134/S0036024418100138

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