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Facile Hydrothermal Synthesis of Anatase TiO2 Hollow Nanospheres with Enhanced Photocatalytic Activity

  • PHYSICAL CHEMISTRY OF NANOCLUSTERS AND NANOMATERIALS
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Abstract

TiO2 nanospheres with hollow structure were obtained by a facile hydrothermal process at the temperature of 200°C. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscope (TEM), Raman spectrum (Raman), UV–Vis absorption spectroscopy (UV–Vis) and fluorescence spectra (FL) were used to characterize the samples, and the photocatalytic activity of the products was tested by the degradation of rhodamine B under the UV light. The formation of this hollow structure in samples prepared at 200°C can be interpreted as the preferential dissolution of the internal structure which has higher solubility. When compared with the counterparts prepared at different temperature, the hollow nanospheres showed excellent optical properties and enhanced photocatalytic acivity which can be attributed to the special hollow structure and the resulting large surface area.

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REFERENCES

  1. A. Fujishima and M. Honda, Nature (London, U.K.) 238, 37 (1972).

    Article  CAS  Google Scholar 

  2. X. Yang, Y. Wang, L. Xu, X. Yu, and Y. Guo, J. Phys. Chem. C 112, 11481 (2008).

    Article  CAS  Google Scholar 

  3. D. Dvoranová, V. Brezová, M. Mazúr, and M. A. Malati, Appl. Catal., B 37, 91 (2002).

    Article  Google Scholar 

  4. S. Y. Huang, L. Kavan, I. Exnar, and M. Gratzel, J. Electrochem. Soc. 142, L142 (1995).

    Article  CAS  Google Scholar 

  5. L. L. Fields, J. P. Zheng, Y. Cheng, and P. Xiong, Appl. Phys. Lett. 88, 263102 (2006).

    Article  CAS  Google Scholar 

  6. E. Bae and W. Choi, Environ. Sci. Technol. 37, 147 (2003).

    Article  CAS  PubMed  Google Scholar 

  7. D. V. Bavykin, V. N. Parmon, A. A. Lapkin, and F. C. Walsh, J. Mater. Chem. 14, 3370 (2004).

    Article  CAS  Google Scholar 

  8. Y. Zhou, Y. T. Wang, M. Y. Li, X. Z. Li, Q. Yi, P. Deng, and H. Y. Wu, Mater. Res. Bull. 66, 115 (2015).

    Article  CAS  Google Scholar 

  9. Y. Jun, J. H. Park, and M. G. Kang, Chem. Commun. 48, 6456 (2012).

    Article  CAS  Google Scholar 

  10. A. K. Patra, A. Dutta, and A. Bhaumik, Appl. Mater. Interfaces 4, 5022 (2012).

    Article  CAS  Google Scholar 

  11. J. Zhu, W. Zheng, B. He, J. Zhang, and M. Anpo, J. Mol. Catal. A: Chem. 216, 35 (2004).

    Article  CAS  Google Scholar 

  12. C. T. Hsieh, W. S. Fan, W. Y. Chen, and J. Y. Lin, Sep. Purif. Technol. 67, 312 (2009).

    Article  CAS  Google Scholar 

  13. J. G. Yu, H. T. Guo, S. A. Davis, and S. Mann, Adv. Funct. Mater. 16, 2035 (2006).

    Article  CAS  Google Scholar 

  14. B. Wang, X. Y. Lu, L.K. Yu, J. Xuan, M. K. H. Leung, and H. F. Guo, CrystEngComm 16, 10046 (2014).

    Article  CAS  Google Scholar 

  15. X. F. Li, K. L. Lv, K. J. Deng, J. F. Tang, R. Su, J. Sun, and L. Q. Chen, Mater. Sci. Eng. B 158, 40 (2009).

    Article  CAS  Google Scholar 

  16. H. C. Zeng, Curr. Nanosci. 3, 177 (2007).

    Article  CAS  Google Scholar 

  17. J. F. Lan, J. H. Cai, L. L. Si, C. J. Yang, and B. Li, Ceram. Int. 41, 7937 (2015).

    Article  CAS  Google Scholar 

  18. H. T. Wu, J. Fan, E. Z. Liu, X. Y. Hu, Y. N. Ma, X. Fan, Y. Y. Li, and C. N. Tang, J. Alloys Compd. 623, 298 (2015).

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

This work was supported by the Anhui Provincial Natural Science Foundation of China (1508085SME219).

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Correspondence to Fanming Meng.

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Yujie Zha, Meng, F., Ding, B. et al. Facile Hydrothermal Synthesis of Anatase TiO2 Hollow Nanospheres with Enhanced Photocatalytic Activity. Russ. J. Phys. Chem. 92, 1772–1776 (2018). https://doi.org/10.1134/S0036024418090364

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  • DOI: https://doi.org/10.1134/S0036024418090364

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