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Kinetic Features of the Formation of Zinc Complex with Hexa(m-Trifluoromethylphenyl)benzoporphyrazine in a Nitrogen-Containing Base–Benzene System

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

The effect n-butylamine, tert-butylamine, piperidine, and morpholine additives have on the kinetics of complex formation between zinc acetate and hexa(m-trifluoromethylphenyl)benzoporphyrazine in benzene is studied. A possible scheme for their complexation is proposed. It is established that the rate and activation parameters of the process are affected by the proton-acceptor capacity of the base and its spatial structure.

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Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, 153000, Ivanovo, Russia

    O. A. Petrov

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  1. O. A. Petrov
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Correspondence to O. A. Petrov.

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Translated by O. Kadkin

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Petrov, O.A. Kinetic Features of the Formation of Zinc Complex with Hexa(m-Trifluoromethylphenyl)benzoporphyrazine in a Nitrogen-Containing Base–Benzene System. Russ. J. Phys. Chem. 92, 1664–1669 (2018). https://doi.org/10.1134/S0036024418090200

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  • DOI: https://doi.org/10.1134/S0036024418090200

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