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Structural Properties and State of a Zirconium Dioxide Surface Layer Modified with Mе3+ Cations

  • PHYSICAL CHEMISTRY OF SURFACE PHENOMENA
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Abstract

The effect Ме3+ (Al, Y, Sc, Fe, and Mn) cations on the structural properties and state of a zirconium dioxide surface layer is investigated. The thermal stability of the Ме3+ solid solutions based on a metastable zirconium dioxide modification is established via X-ray diffraction analysis. It is shown using X‑ray photoelectron spectroscopy that the distribution of surface–volume cationic modifier is determined by the type of cation. In Al-, Fe-, and Mn-ZrO2 systems, modifiers are mainly distributed over a surface; in Y and Sc-ZrО2, modifiers are distributed uniformly. The nature of the cation distribution affects the thermal stability of the solid solutions formed.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 660036, Krasnoyarsk, Russia

    L. I. Kuznetsova, A. V. Obukhova, G. N. Bondarenko, O. Yu. Fetisova, Yu. L. Mikhlin & P. N. Kuznetsov

  2. Siberian Federal University, 660041, Krasnoyarsk, Russia

    S. D. Kirik

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  1. L. I. Kuznetsova
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  2. A. V. Obukhova
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  3. G. N. Bondarenko
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  4. O. Yu. Fetisova
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  5. Yu. L. Mikhlin
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  6. S. D. Kirik
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  7. P. N. Kuznetsov
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Correspondence to A. V. Obukhova.

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Translated by E. Bondareva

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Kuznetsova, L.I., Obukhova, A.V., Bondarenko, G.N. et al. Structural Properties and State of a Zirconium Dioxide Surface Layer Modified with Mе3+ Cations. Russ. J. Phys. Chem. 92, 1799–1805 (2018). https://doi.org/10.1134/S0036024418090145

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  • DOI: https://doi.org/10.1134/S0036024418090145

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