Abstract
Mixing enthalpies of melts of the binary Sb–Yb system have been determined for the first time in the ranges 0 < x Yb < 0.155 at 960–1030 K and 0.89 < x Yb < 1 at 1140 K. It has been found that the melts form with great exothermic effects, and the partial enthalpies of the components at infinite dilution are: \(\Delta \bar H_{Sb}^\infty \) =–260, \(\Delta \bar H_{Sb}^\infty \) =–205 kJ/mol. An ideal associated solution model has been selected to describe the temperature and concentration dependences of thermodynamic properties of the melts, and the parameters of the model have been optimized through self-consistent analysis of the available data on the phase diagram. The model description allows to calculate the Gibbs energies and entropies of mixing of the melts, the activities of the components and the molar fractions of the associates, and the enthalpies and entropies of formation of the solid phases.
Similar content being viewed by others
References
J. Y. Chan, M. M. Olmstead, and S. M. Kauzlarich, Chem. Mater. 10, 3583 (1998).
I. R. Fisher, T. A. Wiener, S. L. Bud’ko, and P. C. Canfield, Phys. Rev. B 59, 13829 (1999).
S. R. Brown, S. M. Kauzlarich, F. Gascoin, and G. J. Snyder, Chem. Mater. 18, 1873 (2006).
J. N. Pratt and K. S. Chua, Final Report No. 2027 (Dept. Phys. Metall. Sci. Mater., Univ. Birmingham, UK, 1970).
F. R. De Boer, R. Boom, W. C. M. Mattens, et al., Cohesion in Metals, Transition Metal Alloys (North-Holland, Amsterdam, 1988).
C. Colinet, A. Pasturel, A. Percheron-Guegan, and J. C. Achard, J. Less-Common Met. 102, 167 (1984); J. Less-Common Met. 102, 239 (1984).
G. Borzone, A. Borsese, A. Saccone, and R. Ferro, J. Less-Common Met. 65, 253 (1979).
A. Borsese, G. Borzone, D. Mazzone, and R. Ferro, J. Less-Common Met. 79, 57 (1981).
G. Borzone, A. Borsese, G. Zanicchi, and R. Ferro, J. Therm. Anal. 25, 433 (1982).
A. Borsese, R. Ferro, R. Capelli, and S. Delfino, J. Less-Common Met. 55, 77 (1977).
G. Borzone, A. Borsese, S. Delfino, and R. Ferro, Zeitschr. Metallk. 76, 208 (1985).
G. Sh. Viksman and S. P. Gordienko, Izv. Akad. Nauk SSSR, Neorg. Mater. 20, 1441 (1984).
V. I. Goryacheva, A. V. Nikol’skaya, and Ya. I. Gerasimov, Dokl. Akad. Nauk SSSR 197, 389 (1971).
G. Borzone, M. L. Fornasini, N. Parodi, and R. Ferro, Intermetallics 8, 189 (2000).
R. Ferro, G. Borzone, and G. Cacciamani, Thermochim. Acta 129, 99 (1988).
V. I. Goryacheva, Ya. I. Gerasimov, and V. P. Vasil’ev, Zh. Fiz. Khim. 55, 1080 (1981).
G. Cacciamani, G. Borzone, N. Parodi, and R. Ferro, Zeitschr. Metallk. 87, 562 (1996).
K. S. Chua and J. N. Pratt, Thermochim. Acta 8, 409 (1974).
Ya. I. Gerasimov, V. I. Goryacheva, and V. P. Vasil’ev, Dokl. Akad. Nauk SSSR 247, 135 (1979).
V. D. Abulkhaev, Inorg. Mater. 35, 431 (1999).
H. Okamoto, J. Phase Equilib. 29, 473 (2008).
X. J. Liu, S. X. Gan, Z. S. Li, et al., CALPHAD: Comput. Coupling Phase Diagrams Thermochem. 37, 132 (2012).
M. Ivanov, V. Berezutski, and N. Usenko, J. Mater. Res. 102, 277 (2011).
A. T. Dinsdale, CALPHAD: Comput. Coupling Phase Diagrams Thermochem. 15, 319 (1991).
M. I. Ivanov, V. V. Berezuts’kii, M. O. Shevchenko, et al., Dopov. NAN Ukr., No. 8, 90 (2013).
V. G. Kudin, M. A. Shevchenko, I. V. Mateiko, and V. S. Sudavtsova, Zh. Fiz. Khim. 87, 364 (2013).
V. S. Sudavtsova, M. I. Ivanov, V. V. Berezutskii, et al., Zh. Fiz. Khim. 86, 1311 (2012).
M. A. Shevchenko, V. G. Kudin, N. G. Kobylinskaya, and V. S. Sudavtsova, Ukr. Khim. Zh. 78 (6), 96 (2012).
M. A. Shevchenko, M. I. Ivanov, V. V. Berezutskii, and V. S. Sudavtsova, Russ. J. Phys. Chem. A 90, 723 (2016).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.S. Sudavtsova, M.A. Shevchenko, M.I. Ivanov, V.V. Berezutskii, V.G. Kudin, K.Yu. Pastushenko, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 7, pp. 1102–1110.
The article was translated by the authors.
Rights and permissions
About this article
Cite this article
Sudavtsova, V.S., Shevchenko, M.A., Ivanov, M.I. et al. Thermodynamic properties of alloys of the binary Sb–Yb system. Russ. J. Phys. Chem. 91, 1174–1182 (2017). https://doi.org/10.1134/S0036024417070287
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024417070287