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Visible and near-IR spectroscopy of endohedral Gd@C82(C 2v ) and Ho@C82(C 2v ) metallofullerenes and their monoanions

  • Structure of Matter and Quantum Chemistry
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Abstract

Solutions of endohedral Gd@C82(C 2v ) and Ho@C82(C 2v ) metallofullerenes are studied by means of visible and near-IR spectroscopy upon their conversion from neutral to the anionic form via a redox reaction with the electron donor potassium perchlorotriphenylmethide K(18-crown-6)[C(C6Cl5)3]. The concentrations of the studied solutions of endohedral Gd@C82(C 2v ) and Ho@C82(C 2v ) metallofullerenes in o-dichlorobenzene were determined from the spectroscopic data, and their molar extinction coefficients are calculated.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    I. E. Kareev, V. M. Nekrasov, A. E. Dutlov, V. M. Martynenko & V. P. Bubnov

  2. Faculty of Fundamental Physical and Chemical Engineering, Moscow State University, Moscow, 119991, Russia

    V. M. Nekrasov & A. E. Dutlov

  3. Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), 08193, Bellaterra, Spain

    E. Laukhina, J. Veciana & C. Rovira

Authors
  1. I. E. Kareev
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  2. V. M. Nekrasov
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  3. A. E. Dutlov
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  4. V. M. Martynenko
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  5. V. P. Bubnov
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  6. E. Laukhina
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  7. J. Veciana
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  8. C. Rovira
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Corresponding author

Correspondence to I. E. Kareev.

Additional information

Original Russian Text © I.E. Kareev, V.M. Nekrasov, A.E. Dutlov, V.M. Martynenko, V.P. Bubnov, E. Laukhina, J. Veciana, C. Rovira, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 3, pp. 492–499.

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Kareev, I.E., Nekrasov, V.M., Dutlov, A.E. et al. Visible and near-IR spectroscopy of endohedral Gd@C82(C 2v ) and Ho@C82(C 2v ) metallofullerenes and their monoanions. Russ. J. Phys. Chem. 91, 536–542 (2017). https://doi.org/10.1134/S0036024417030104

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  • DOI: https://doi.org/10.1134/S0036024417030104

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