Skip to main content
SpringerLink
Log in

Reduction of carbon dioxide by hydrogen on metal–carbon catalysts under supercritical conditions

  • Chemical Kinetics and Catalysis
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The reduction of carbon dioxide with hydrogen on metal–carbon (Ru, Rh, Ir) catalysts is investigated under supercritical conditions for the first time. High selectivity (close to 100%) toward methanation with good stability of catalytic activity is observed for Ru- and Rh-containing catalyst, while the preferred reduction to CO is observed for Ir/C catalyst.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. Wang, S. Wang, X. Ma, and J. Gon., Chem. Soc. Rev. 40, 3703 (2011).

    Article  CAS  Google Scholar 

  2. I. Oma., Catal. Today 115, 33 (2006).

    Article  Google Scholar 

  3. G. Centi and S. Perathone., Catal. Today 148, 191 (2009).

    Article  CAS  Google Scholar 

  4. M. Mikkelsen, M. Jorgensen, and F. C. Kreb., Energy Environ. Sci. 3, 43 (2010).

    Article  CAS  Google Scholar 

  5. J. Ma, N. N. Sun, X. L. Zhang, et al., Catal. Today 148, 221 (2009).

    Article  CAS  Google Scholar 

  6. W. L. Dai, S. L. Luo, S. F. Yin, and C. T. A., Appl. Catal. A 366, 2 (2009).

    Article  CAS  Google Scholar 

  7. S. K. Hoekman, A. Broch, C. Robbins, and R. Purcel., Int. J. Greenhouse Gas Control 4, 44 (2010).

    Article  CAS  Google Scholar 

  8. A. L. Kustov, A. M. Frey, K. E. Larsen, et al., Appl. Catal. A 320, 98 (2007).

    Article  CAS  Google Scholar 

  9. Z. Kowalczyk, K. Stolecki, W. Rarog-Pilecka, et al., Appl. Catal. A 342, 35 (2008).

    Article  CAS  Google Scholar 

  10. S. Zhang, Y. Chen, F. Li, et al., Catal. Today 115, 61 (2006).

    Article  CAS  Google Scholar 

  11. J. M. Sun, S. Fujita, and M. Ara., J. Organomet. Chem. 690, 3490 (2005).

    Article  CAS  Google Scholar 

  12. P. G. Jesso., J. Supercrit. Fluids 38, 211 (2006).

    Article  Google Scholar 

  13. P. G. Jessop, Y. Hsiao, T. Ikariya, and R. Noyor., J. Am. Chem. Soc. 116, 8851 (1994).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    V. I. Bogdan, A. E. Koklin, D. O. Kozak & L. M. Kustov

  2. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    V. I. Bogdan & L. M. Kustov

Authors
  1. V. I. Bogdan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. E. Koklin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. O. Kozak
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. M. Kustov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. M. Kustov.

Additional information

Original Russian Text © V.I. Bogdan, A.E. Koklin, D.O. Kozak, L.M. Kustov, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 12, pp. 1785–1790.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bogdan, V.I., Koklin, A.E., Kozak, D.O. et al. Reduction of carbon dioxide by hydrogen on metal–carbon catalysts under supercritical conditions. Russ. J. Phys. Chem. 90, 2352–2357 (2016). https://doi.org/10.1134/S0036024416120050

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024416120050

Keywords

Search

Navigation