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Paramagnetic properties of triple molybdates CsNa5M3(MoO4)6 (M = Ni, Co, Mn)

  • Photochemistry and Magnetochemistry
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Abstract

The static magnetization of CsNa5M3(MoO4)6 single phase molybdates, where M = Co, Ni, and Mn, is measured at 4–300 K in magnetic fields of up to 20 kOe. It is shown that the materials are paramagnetic. Magnetization as a function of temperature is described using the Curie–Weiss law. The intrinsic magnetic moments of the phases are found to be 9.759 (Co), 6.958 (Ni), and 12.203 Bohr magnetons for manganese molybdates. It is concluded that the charge state of Co, Ni, and Mn cations in the compounds is +2.

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References

  1. M. Lacerda, J. T. S. Irvine, F. P. Glasser, et al., Nature 332, 525 (1988).

    Article  CAS  Google Scholar 

  2. J. Jeevaratnam, L. S. D. Glasser, and F. P. Glasser, Nature 194 (4830), 764 (1962).

    Article  CAS  Google Scholar 

  3. H. Boysen, M. Lerch, A. Stys, et al., Acta Crystallogr. B 63, 675 (2007).

    Article  CAS  Google Scholar 

  4. H. Hosono, Sci. Technol. Adv. Mater. 5, 409 (2004).

    Article  CAS  Google Scholar 

  5. JP Patent No. 2005089847 (2005).

  6. RF Patent No. 2459781, Byull. Izobret. No. 24 (2012).

  7. RF Patent No. 2492914, Byull. Izobret. No. 3 (2013).

  8. WO Patent No. 2012077658 (2012).

  9. WO Patent No. 2013094346 (2013).

  10. JP Patent No. 2010016104 (2010).

  11. JP Patent No. 2010261086 (2010).

  12. JP Patent No. 2007260244 (2007)

  13. WO Patent No. 2013145807 (2013).

  14. WO Patent No. 2013145805 (2013).

  15. S. F. Solodovnikov, P. V. Klevtsov, L. A. Glinskaya, et al., Sov. Phys. Crystallogr. 32, 359 (1987).

    Google Scholar 

  16. V. Klemm, Magnetochemistry (Goskhimizdat, Moscow, 1939) [in Russian].

    Google Scholar 

  17. P. Selwood, Magnetochemistry (Interscience, New York, 1956).

    Google Scholar 

  18. S. V. Vonsovskii, Magnetism (Nauka, Moscow, 1971) [in Russian].

    Google Scholar 

  19. V. T. Kalinnikov and Yu. V. Rakitin, Introduction to Magnetochemistry: Method of Static Magnetic Susceptibility in Chemistry (Nauka, Moscow, 1980).

    Google Scholar 

  20. R. L. Carlin, Magnetochemistry (Springer, Berlin, 1986).

    Book  Google Scholar 

  21. Yu. V. Rakitin and V. T. Kalinnikov, Advanced Magnetochemistry (Nauka, St. Petersburg, 1994) [in Russian].

    Google Scholar 

  22. D. G. Kellerman, Magnetochemistry (Ural. Gos. Univ., Ekaterinburg, 2008) [in Russian].

    Google Scholar 

  23. V. N. Yudin, E. S. Zolotova, Z. A. Solodovnikova, et al., in Proceedings of the 9th Seminar of Siberian Branch of RAS–Ural Branch of RAS on Thermodynamics and Material Science, Novosibirsk, 2014, p. 151.

    Google Scholar 

  24. V. N. Yudin, E. S. Zolotova, Z. A. Solodovnikova, et al., in Proceedings of the 2nd All-Russia with International Participation Conference of Young Scientists on Ecologically Safe and and Resource-Saving Technologies and Materials (Buryat. Gos. Univ., Ulan-Ude, 2014), p. 122.

    Google Scholar 

  25. G. M. Sheldrick, SHELX97, Release 97-2 (Univ. of Göttingen, Göttingen, Germany, 1997).

    Google Scholar 

  26. P. B. Moore, Am. Mineralog. 56, 1955 (1971).

    CAS  Google Scholar 

  27. G. V. Bazuev and A. V. Korolev, Phys. Solid State 50, 43 (2008).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620137, Russia

    S. N. Shkerin & A. S. Tolkacheva

  2. Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620016, Russia

    S. A. Uporov

  3. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. N. Yudin, S. F. Solodovnikov & E. S. Zolotova

  4. National Research Novosibirsk State University, Novosibirsk, 630090, Russia

    S. F. Solodovnikov

  5. Institute of Materials Science and Metallurgy, Ural Federal University, Yekaterinburg, 620083, Russia

    A. S. Tolkacheva

Authors
  1. S. N. Shkerin
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  2. S. A. Uporov
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  3. V. N. Yudin
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  4. S. F. Solodovnikov
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  5. E. S. Zolotova
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  6. A. S. Tolkacheva
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Corresponding author

Correspondence to S. N. Shkerin.

Additional information

Original Russian Text © S.N. Shkerin, S.A. Uporov, V.N. Yudin, S.F. Solodovnikov, E.S. Zolotova, A.S. Tolkacheva, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 11, pp. 1734–1738.

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Shkerin, S.N., Uporov, S.A., Yudin, V.N. et al. Paramagnetic properties of triple molybdates CsNa5M3(MoO4)6 (M = Ni, Co, Mn). Russ. J. Phys. Chem. 90, 2292–2296 (2016). https://doi.org/10.1134/S0036024416110248

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  • DOI: https://doi.org/10.1134/S0036024416110248

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