Skip to main content
SpringerLink
Log in

Thermodynamic characteristics of sorption extraction and chromatographic separation of anionic complexes of erbium and cerium with Trilon B on weakly basic anionite

  • Physical Chemistry of Separation Processes: Chromatography
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The adsorption of anionic complexes of erbium with Trilon B on D-403 anionite is studied at ionic strengths of 1 and 2 mol/kg (NaNO3) and temperatures of 298 and 343 K. The values of the stability constants of complex ions of REE with Trilon B and the Gibbs energies of complexation are calculated. The values of the Gibbs energy and the enthalpy and entropy of ion exchange are determined. Using the obtained thermo-dynamic and sorption characteristics, the possible separation of anionic complexes of erbium and cerium with Trilon B is demonstrated via frontal ion-exchange chromatography. A series of sorption capacities of anionic complexes of cerium, yttrium, and erbium is presented using the values of the Gibbs energy of ion exchange.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. Tertre, G. Berger, S. Caste, et al., Geochim. Cosmochim. Acta 69, 4937 (2005).

    Article  CAS  Google Scholar 

  2. R. Akkaya, Desalinat. Water Treat. 50, 180 (2013).

    Article  Google Scholar 

  3. G. R. Kolonin, O. L. Gas’kova, and G. P. Shironosova, Vestn. Otd. Nauk Zemle RAN, No. 1 (21), 1 (2003). http://wwwscgisru/russian/cp1251/h_dgggms/1-2003/ informbul-1/hydroterm-7pdf

    Google Scholar 

  4. A. A. Arkhipova, M. A. Statkus, T. I. Tikhomirova, et al., Sorbtsion. Khromatogr. Protsessy 14, 214 (2014).

    CAS  Google Scholar 

  5. N. M. Dyatlova, V. Ya. Temkina, and K. I. Popov, Complexons and Complexonats of Metals (Khimiya, Moscow, 1988) [in Russian].

    Google Scholar 

  6. E. Tertre, A. Hofmann, and G. Berger, Geochim. Cosmochim. Acta, No. 72, 1043 (2008).

    Article  CAS  Google Scholar 

  7. N. Das and D. Das, J. Rare Earths 31, 933 (2013).

    Article  CAS  Google Scholar 

  8. O. V. Cheremisina, D. E. Chirkst, and M. A. Ponomareva, Russ. J. Phys. Chem. A 87, 1562 (2013).

    Article  CAS  Google Scholar 

  9. S. B. Savin, Arsenazo III (Atomizdat, Moscow, 1966) [in Russian].

    Google Scholar 

  10. Short Handbook of Physical Chemical Values, Ed. by A. A. Ravdel’ and A. M. Ponomareva, 10th ed. (Ivan Fedorov, St. Petersburg, 2003) [in Russian].

  11. I. V. Mironov, Medium Effects on Complex Formation in Electrolyte Solutions (Inst. Neorg. Khim. SO RAN, Novosibirsk, 2003) [in Russian].

    Google Scholar 

  12. O. V. Cheremisina, M. A. Ponomareva, D. E. Chirkst, O. L. Lobacheva, and I. A. Shul’gin, Russ. J. Phys. Chem. A 89, 119 (2015).

  13. K. B. Yatsimirskii, N. A. Kostromina, Z. A. Sheka, et al., Chemistry of Rare-Earth Complexes (Naukova Dumka, Kiev, 1966) [in Russian].

    Google Scholar 

  14. L. I. Martynenko, Russ. Chem. Rev. 60, 1008 (1991).

    Article  Google Scholar 

  15. V. P. Vasil’ev, Thermodynamic Properties of Solutions of Electrolytes (Vyssh. Shkola, Moscow, 1982) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National Mineral Resources (Mining) University, St. Petersburg, 199106, Russia

    O. V. Cheremisina, M. A. Ponomareva & V. N. Sagdiev

Authors
  1. O. V. Cheremisina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. A. Ponomareva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. N. Sagdiev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. V. Cheremisina.

Additional information

Original Russian Text © O.V. Cheremisina, M.A. Ponomareva, V.N. Sagdiev, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 3, pp. 443–450.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Cheremisina, O.V., Ponomareva, M.A. & Sagdiev, V.N. Thermodynamic characteristics of sorption extraction and chromatographic separation of anionic complexes of erbium and cerium with Trilon B on weakly basic anionite. Russ. J. Phys. Chem. 90, 664–670 (2016). https://doi.org/10.1134/S0036024416030079

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024416030079

Keywords

Search

Navigation