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One-pot synthesis and photoluminescence properties of core/porous-shell olive-like BaWO4 microstructure by a template-assisted hydrothermal method

  • Photochemistry and Magnetochemistry
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Abstract

Core/porous-shell olive-like crystalline BaWO4 is synthesized by a combined simple hydrothermal method and soft template approach. The prepared product shows an olive-like shape with diameter of ∼2 μm, length of ∼4 μm, and the thickness of the shell of about 65 nm, which are orderly assembled by many nanoparticles. A possible formation mechanism of olive-like BaWO4 microstructure involving interfacial recognization of ions, nucleation, aggregation, in situ growth and Ostwald ripening process is proposed. Polyacrylic acid sodium (PAAS) as a template plays an important role in inducing the nucleation and growth of olive-like BaWO4 microcrystalline. Other shapes of BaWO4 microcrystalline are also fabricated by varying the concentration of PAAS and Ba2+. The olive-like product with a core-shell structure which exists a large number of pores on crystal surface shows excellent photoluminescence property, which have potentially applied prospects in fields such as light display systems etc.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601, P. R. China

    Suyue Zhang, Yunlong Wang, Cuiping Wang, Hui Zhang, Yuhua Shen & Anjian Xie

  2. Lab for Clean Energy and Green Catalysis, Anhui University, Hefei, 230601, P. R. China

    Suyue Zhang, Cuiping Wang, Hui Zhang, Yuhua Shen & Anjian Xie

Authors
  1. Suyue Zhang
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  2. Yunlong Wang
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  3. Cuiping Wang
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  4. Hui Zhang
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  5. Yuhua Shen
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  6. Anjian Xie
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Correspondence to Anjian Xie.

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Zhang, S., Wang, Y., Wang, C. et al. One-pot synthesis and photoluminescence properties of core/porous-shell olive-like BaWO4 microstructure by a template-assisted hydrothermal method. Russ. J. Phys. Chem. 90, 498–503 (2016). https://doi.org/10.1134/S0036024416020321

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  • DOI: https://doi.org/10.1134/S0036024416020321

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