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Synthesis and properties of dicationic ionic liquids containing a siloxane structural moiety

  • Chemical Kinetics and Catalysis
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Abstract

Five new ionic liquids formed by doubly charged cations containing a siloxane moiety and bis(trifluoromethylsulfonyl) imide anion are synthesized and characterized. Their thermal stability is studied by means of TGA; melting points (glass transition temperatures) and densities are measured. The temperature dependences of kinematic viscosity of the obtained ionic liquids are presented along with their approximations by the Vogel–Tammann–Fulcher equation.

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References

  1. S. Zhang, X. Lu, Q. Zhou, and X. Li, Ionic Liquids: Physicochemical Properties (Elsevier, Amsterdam, 2009).

    Google Scholar 

  2. E. A. Chernikova, L. M. Glukhov, L. M. Kustov, et al., Russ. Chem. Rev. 84, 875 (2015).

    Article  CAS  Google Scholar 

  3. M. A. A. Rocha and C. F. R. A. C. Lima, L. R. Gomes, et al., J. Phys. Chem. B 115, 10919 (2011).

    Article  CAS  Google Scholar 

  4. A. Deyko, K. R. J. Lovelock, J.-A. Corfield, et al., Phys. Chem. Chem. Phys. 11, 8544 (2009).

    Article  CAS  Google Scholar 

  5. R. Tacke and R. Niedner, Z. Naturforsch. B: Anorg. Chem., Org. Chem. 33, 412 (1978).

    Article  Google Scholar 

  6. E. Lukevits, A. A. Kimenis, M. M. Veveris, et al., Khim.-Farm. Zh. 16, 1201 (1982).

    Google Scholar 

  7. E. Lukevits, V. Luse, I. Zitsmane, et al., Khim. Geterotsikl. Soedin. 27, 1653 (1991).

    Google Scholar 

  8. US Patent No. 8027148.

  9. M. G. Voronkov, S. V. Kirpichenko, A. T. Abrosimova, et al., Zh. Org. Khim. 52, 2055 (1982).

    CAS  Google Scholar 

  10. Yu. V. Svetkin and Yu. R. Kolesnik, Zh. Org. Khim. 52, 907 (1982).

    CAS  Google Scholar 

  11. Soonho Lee, Youngtae Jeon, Youngdon Lim, et al., Bull. Korean Chem. Soc. 34, 2583 (2013).

    Article  CAS  Google Scholar 

  12. C. Rimniceanu, M. Cazacu, M. Marcu, and I. Rimniceanu, Rev. Roum. Chim. 47, 551 (2002).

    CAS  Google Scholar 

  13. A. R. Bassindale, M. Borbaruah, S. J. Glynn, et al., J. Chem. Soc., Perkin Trans. 10, 2099 (1999).

    Article  Google Scholar 

  14. H. Niedermeyer, M. A. Ab Rani, P. D. Lickiss, et al., Phys. Chem. Chem. Phys. 12, 2018 (2010).

    Article  CAS  Google Scholar 

  15. S. Bulut, M. A. Ab Rani, T. Welton, et al., ChemPhysChem 13, 1802 (2012).

    Article  CAS  Google Scholar 

  16. H. Shirota, J. F. Wishart, and E. W. Castner, J. Phys. Chem. B 111, 4819 (2007).

    Article  CAS  Google Scholar 

  17. GB Patent No. 1006729.

  18. US Patent No. 7129202.

  19. E. A. Chernikova, L. M. Glukhov, V. G. Krasovskiy, L. M. Kustov, and A. A. Koroteev, Russ. Chem. Bull. 63, 2702 (2014).

    Article  CAS  Google Scholar 

  20. J. Lafay, L. Latxague, C. Lacroix, and G. Déléris, Phosph. Sulf. Silic. Rel. Elem. 102, 155 (1995).

    Article  CAS  Google Scholar 

  21. C. Däschlein, J. O. Bauer, and C. Strohmann, Angew. Chem., Int. Ed. Engl. 48, 8074 (2009).

    Article  Google Scholar 

  22. M. V. Sobolevskii, I. I. Skorokhodov, and K. P. Grinevich, Oligoorganosiloxanes. Properties, Synthesis, Application, Ed. by M. V. Sobolevskii (Khimiya, Moscow, 1985) [in Russian].

  23. Solution Chemistry Research Progress, Ed. by D. V. Bostrelli (Nova Science, New York, 2008).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    L. M. Glukhov, V. G. Krasovskiy, E. A. Chernikova, G. I. Kapustin & L. M. Kustov

  2. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    L. M. Kustov

  3. Moscow Aviation Institute, Moscow, 125993, Russia

    A. A. Koroteev

Authors
  1. L. M. Glukhov
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  2. V. G. Krasovskiy
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  3. E. A. Chernikova
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  4. G. I. Kapustin
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  5. L. M. Kustov
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  6. A. A. Koroteev
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Corresponding author

Correspondence to L. M. Glukhov.

Additional information

Original Russian Text © L.M. Glukhov, V.G. Krasovskiy, E.A. Chernikova, G.I. Kapustin, L.M. Kustov, A.A. Koroteev, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 12, pp. 1858–1863.

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Glukhov, L.M., Krasovskiy, V.G., Chernikova, E.A. et al. Synthesis and properties of dicationic ionic liquids containing a siloxane structural moiety. Russ. J. Phys. Chem. 89, 2204–2209 (2015). https://doi.org/10.1134/S0036024415120134

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  • DOI: https://doi.org/10.1134/S0036024415120134

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