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Solute–solvent interactions in solutions of 2-hydroxy-5-chloro-3-nitroacetophenone isonicotinoylhydrazone in N,N-dimethylformamide at 298–313 K according to ultrasonic and viscometric data

  • Chemical Thermodynamics and Thermochemistry
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Abstract

Density (ρ), speed of sound (u), and viscosity (η), measurements have been carried on 2-hydroxy- 5-chloro-3-nitroacetophenone isonicotinoylhydrazone (HCNAIH) in N,N-dimethylformamide at 298.15, 303.15, 308.15, and 313.15 K. Adiabatic compressibility (βs), intermolecular free length (L f), acoustic impedance (Z), internal pressure (P int), the apparent molar volume (V ф), limiting apparent molar volume (V ф 0), partial molar expansibility (ф 0E ), apparent molar adiabatic compressibility (K ф), limiting apparent molar adiabatic compressibility (K ф 0), viscosity B coefficients of Jones–Dole equation have been calculated. The activation free energy (Δμ 02 *) for viscous flow in solution have been calculated from B coefficient and partial molar volume data. The calculated parameters are used to interpret the solute–solvent interactions and structure forming/breaking ability of solute in DMF.

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Authors and Affiliations

  1. Department of Chemistry, Sant Gadge Baba Amravati University, Amravati, 444 602, India

    A. B. Dikkar, G. B. Pethe & A. S. Aswar

Authors
  1. A. B. Dikkar
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  2. G. B. Pethe
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  3. A. S. Aswar
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Correspondence to A. S. Aswar.

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Dikkar, A.B., Pethe, G.B. & Aswar, A.S. Solute–solvent interactions in solutions of 2-hydroxy-5-chloro-3-nitroacetophenone isonicotinoylhydrazone in N,N-dimethylformamide at 298–313 K according to ultrasonic and viscometric data. Russ. J. Phys. Chem. 89, 2197–2203 (2015). https://doi.org/10.1134/S0036024415120109

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  • DOI: https://doi.org/10.1134/S0036024415120109

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