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Thermodynamic parameters of the first order in low-concentration binary alloys

  • Chemical Thermodynamics and Thermochemistry
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Abstract

Thermodynamic parameters of the first order (Wagner interaction parameter ε (2)2 , enthalpy, and entropy parameter σ (2)2 ) in low-concentration liquid binary alloys are considered. The values of these parameters for 32 binary systems are estimated from experimental data. A system of classification is proposed for the obtained data. These data are compared to similar data for aqueous solutions of nonelectrolytes. A qualitative explanation of the obtained differences is given.

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Authors and Affiliations

  1. Vologda State University, Vologda, 160000, Russia

    L. A. Bol’shov & S. K. Korneichuk

Authors
  1. L. A. Bol’shov
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  2. S. K. Korneichuk
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Correspondence to S. K. Korneichuk.

Additional information

Original Russian Text © L.A. Bol’shov, S.K. Korneichuk, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 12, pp. 1841–1844.

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Bol’shov, L.A., Korneichuk, S.K. Thermodynamic parameters of the first order in low-concentration binary alloys. Russ. J. Phys. Chem. 89, 2174–2177 (2015). https://doi.org/10.1134/S0036024415120055

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  • DOI: https://doi.org/10.1134/S0036024415120055

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