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Partial molar volumes and viscosities of aqueous hippuric acid solutions containing LiCl and MnCl2 · 4H2O at 303.15 K

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Abstract

Density (ρ) and viscosity (η) of aqueous hippuric acid (HA) solutions containing LiCl and MnCl2 · 4H2O have been studied at 303.15 K in order to understand volumetric and viscometric behavior of these systems. Apparent molar volume (φv) of salts were calculated from density data and fitted to Massons relation and partial molar volumes (φ 0v ) at infinite dilution were determined. Relative viscosity data has been used to determine viscosity A and B coefficients using Jones-Dole relation. Partial molar volume and viscosity coefficients have been discussed in terms of ion-solvent interactions and overall structural fittings in solution.

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References

  1. C. K. Rath, N. C. Rout, S. P. Das, and P. K. Mishra, Ultra Chem. 8, 205 (2012).

    CAS  Google Scholar 

  2. V. Kumar and R. Singh, Ultra Chem. 8, 361 (2012).

    CAS  Google Scholar 

  3. V. K. Syal, S. Chauhan, and M. S. Chauhan, Z. Phys. Chem. 159, 49 (1988).

    Article  CAS  Google Scholar 

  4. M. N. Roy, R. Chanda, and R. K. Das, Phys. Chem. Liq., 1–22 (2011).

    Google Scholar 

  5. M. N. Roy, D. Nandi, and D. K. Hazra, J. Ind. Chem. Soc. 70, 121 (1993).

    CAS  Google Scholar 

  6. M. N. Roy, R. Chanda, R. K. Das, and D. Ekka, J. Chem. Eng. Data 56, 3285 (2011).

    Article  CAS  Google Scholar 

  7. M. N. Roy, D. Ekka, and R. Dewan, Acta Chim. Slov. 58, 792 (2011).

    CAS  Google Scholar 

  8. P. C. Dey, M. A. Motin, T. K. Biswas, and E. M. Huque, Monatsh Chem. 134, 797 (2003).

    Article  CAS  Google Scholar 

  9. M. J. Iqbal and M. A Chaudhry, J. Chem. Thermodyn. 41, 221 (2009).

    Article  CAS  Google Scholar 

  10. S. J. Kharat, J. Mol. Liq. 140, 10 (2008).

    Article  CAS  Google Scholar 

  11. M. N. Roy, A. Banerjee, and P. K. Roy, Int. J. Thermophys. 30, 515 (2009).

    Article  CAS  Google Scholar 

  12. D. P. Gulwade, M. L. Narwade, and K. N. Wadodkar, Ind. J. Chem. A 43, 2102 (2004).

    Google Scholar 

  13. B. Sinha, V. K. Dakua, and M. N. Roy, J. Chem. Eng. Data 52, 1768 (2007).

    Article  CAS  Google Scholar 

  14. A. F. Fucaloro, Y. Pu, K. Cha, A. Williams, and K. Conrad, J. Solut. Chem. 36, 61 (2007).

    Article  CAS  Google Scholar 

  15. P. S. Nikam, R. P. Shewale, A. B. Sawant, and M. Hasan, J. Chem. Eng. Data 50, 487 (2005).

    Article  CAS  Google Scholar 

  16. D. V. Jahagirdar, B. R. Arbad, C. S. Patil, and A. G. Shankarwar, Ind. J. Chem. A 40, 815 (2001).

    Google Scholar 

  17. J. Krakowiak, H. Koziel, and W. Grzybkowski, J. Mol. Liq. 118, 57 (2005).

    Article  CAS  Google Scholar 

  18. A. N. Kannappan and R. Palani, Ind. J. Chem. A 46, 54 (2007).

    Google Scholar 

  19. S. D. Deosarkar, M. S. Menkudle, M. P. Shelke, and T. M. Kalyankar, Russ. J. Phys. Chem. A 88, 342 (2014).

    Article  CAS  Google Scholar 

  20. S. D. Deosarkar, S. M. Deoraye, and T. M. Kalyankar, Russ. J. Phys. Chem. A 88, 1129 (2014).

    Article  CAS  Google Scholar 

  21. S. D. Deosarkar and U. B. Shaikh, Russ. J. Gen. Chem. 83, 2392 (2013).

    Article  CAS  Google Scholar 

  22. S. D. Deosarkar, Russ. J. Phys. Chem. A 87, 1420 (2013).

    Article  CAS  Google Scholar 

  23. S. D. Deosarkar and M. L. Narwade, Russ. J. Phys. Chem. A 87, 1423 (2013).

    Article  CAS  Google Scholar 

  24. S. D. Deosarkar and M. L. Narwade, Rasayan J. Chem. 3, 55 (2010).

    CAS  Google Scholar 

  25. S. D. Deosarkar, H. G. Jahagirdar, and V. B. Talwatkar, Rasayan J. Chem. 3, 755 (2010).

    CAS  Google Scholar 

  26. D. E. Henderson, Analytical Chemistry Laboratory Manual (Trinity College Hartford, 2006).

    Google Scholar 

  27. M. A. Saleh, S. Akhtar, M. S. Ahmed, and M. H. Uddin, Phys. Chem. Liq. 43, 367 (2005).

    Article  CAS  Google Scholar 

  28. J. A. Dean, Lange’s Handbook of Chemistry, 15th ed. (McGraw-Hill, New York, 1999).

    Google Scholar 

  29. G. Jones and M. Dole, J. Am. Chem. Soc. 51, 2950 (1929).

    Article  CAS  Google Scholar 

  30. R. Mathpal, B. K. Joshi, S. Joshi, and N. D. Kandpal, Monatsh. Chem. 137, 375 (2006).

    Article  CAS  Google Scholar 

  31. B. Hawrylak, R. Palepu, and P. R. Tremaine, J. Chem. Thermodyn. 38, 988 (2006).

    Article  CAS  Google Scholar 

  32. D. O. Masson, Philos Mag. 8, 218 (1929).

    Article  CAS  Google Scholar 

  33. A. Ştefaniu, O. Iulian, and O. Ciocirlan, Rev. Roum. Chim. 56, 869 (2011).

    Google Scholar 

  34. B. Sinha, P. K. Roy, and M. N. Roy, Acta Chim. Slov. 57, 651 (2010).

    CAS  Google Scholar 

  35. P. S. Nikam and V. P. Sonawane, Int. J. Chem. Sci. 3, 2010 (2003).

    Google Scholar 

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Authors and Affiliations

  1. School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, 431606, MS, India

    S. D. Deosarkar, P. D. Tawde, A. B. Zinjade & A. I. Shaikh

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  1. S. D. Deosarkar
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  2. P. D. Tawde
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  3. A. B. Zinjade
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  4. A. I. Shaikh
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Correspondence to S. D. Deosarkar.

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Deosarkar, S.D., Tawde, P.D., Zinjade, A.B. et al. Partial molar volumes and viscosities of aqueous hippuric acid solutions containing LiCl and MnCl2 · 4H2O at 303.15 K. Russ. J. Phys. Chem. 89, 1556–1559 (2015). https://doi.org/10.1134/S0036024415090083

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