Abstract
Liquid-crystal films prepared by different procedures and having different thicknesses were studied. A structural phase transition was found in these films at ∼75°C. The nature of this transition was examined by investigating the temperature dependences of the electric capacity and conductivity of the films; the optical absorption and reflection spectra were also studied. It was concluded that the samples contained a ferroelectric phase. The structure of the films was studied by atomic force microscopy. As a result of the structural studies, the peculiarities of the temperature dependences of conductivity and capacity, in particular, the temperature range in which the phase transition was observed were explained.
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References
V. V. Lazarev, L. M. Blinov, S. P. Palto, and S. G. Yudin, Thin Solid Films 516, 8905 (2008).
Z. Wen, Q. Jiang, K. Tatani, and Y. Ozaki, J. Phys. Chem. B 110, 1722 (2006).
N. L. Levshin, P. A. Forsh, S. V. Khlybov, and S. G. Yudin, Vestn. Mosk. Univ., Ser. Fiz. Astron. 66(1), 25 (2011).
M. Glogarova and J. Pavel, Mol. Cryst. Liq. Cryst. 114, 249 (1984).
N. L. Levshin, M. N. Martyshov, P. A. Forsh, et al., Vestn. Mosk. Univ., Ser. Fiz. Astron. 65(4), 89 (2010).
M. P. Jubindo, A. Ezcurra, De la Fuente, et al., Ferroelectrics 85, 199 (1988).
C. Vargel, Corrosion of Aluminium (Elsevier, Amsterdam, 2004).
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Original Russian Text © V.B. Zaitsev, A.V. Zaitseva, N.L. Levshin, P.A. Forsh, S.V. Khlybov, S.G. Yudin, 2014, published in Zhurnal Fizicheskoi Khimii, 2014, Vol. 88, No. 9, pp. 1417–1422.
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Zaitsev, V.B., Zaitseva, A.V., Levshin, N.L. et al. Effect of the synthetic procedure on the properties of thin films of liquid crystals. Russ. J. Phys. Chem. 88, 1585–1589 (2014). https://doi.org/10.1134/S0036024414090325
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DOI: https://doi.org/10.1134/S0036024414090325