Abstract
Relative polarity values and retention indices for a mixture of normal paraffins C5–C10 and alkylbezenes C6–C9 are determined for four types of monolithic capillary columns based on divinylbenzene, ethylene glycol dimethacrylate, pentaerythritol tetraacrylate, and pentaerythritol triacrylate. It is established that the retention of polar sorbates increases with a rise in stationary phase polarity, while the retention of nonpolar compounds grows with a reduction in stationary phase polarity.
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References
L. Rohrschneider, Z. Anal. Chem. 170, 256 (1959).
L. Rohrschneider, J. Chromatogr. 17, 1 (1965).
L. Rohrschneider, J. Chromatogr. 22, 6 (1966).
L. Rohrschneider, Advances in Chromatography (Marcel Dekker, New York, 1967), Vol. 4.
W. O. McReynolds, J. Chromatogr. Sci. 8, 685 (1970).
L. S. Ettre, J. V. Hinshaw, and L. Rohrschneider, Grundbegruffe und Gleichungen der Gaschromatogrphie (Huethig, Heidelberg, 1966).
S. D. Nogare and R. S. Juvet, Gas-Liquid Chromatography (Wiley Interscience, New York, 1962; Nedra, Leningrad, 1966).
G. Guiochon and C. Guillemin, Quantitative Gas Chromatography for Laboratory Analysis and On-Line Process Control (Elsevier, Amsterdam, The Netherlands, 1988; Mir, Moscow, 1991).
A. A. Korolev, V. E. Shiryaeva, T. P. Popova, and A. A. Kurganov, Russ. J. Phys. Chem. A 81, 433 (2007).
A. V. Kozin and A. A. Kurganov, Chromatography for the Benefit of Russia, Ed. by A. A. Kurganov (Granitsa, Moscow, 2007), p. 184 [in Russian].
V. E. Shiryaeva, A. A. Korolev, T. P. Popova, and A. A. Kurganov, Russ. J. Phys. Chem. A 83, 1212 (2009).
T. P. Popova, A. A. Korolev, and V. E. Shiryaeva, in Proceedings of the 9th All-Union Conference on Gas Chromatography (Kuibyshev, 1987).
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Original Russian Text © A.A. Korolev, V.E. Shiryaeva, T.P. Popova, A.A. Kurganov, 2014, published in Zhurnal Fizicheskoi Khimii, 2014, Vol. 88, No. 9, pp. 1442–1445.
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Korolev, A.A., Shiryaeva, V.E., Popova, T.P. et al. Chromatographic characteristics of monolithic capillary columns with different polarities. Russ. J. Phys. Chem. 88, 1609–1612 (2014). https://doi.org/10.1134/S0036024414090209
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DOI: https://doi.org/10.1134/S0036024414090209