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Multistep elution chromatography model of a multicomponent mixture

  • Physical Chemistry of Separation Processes. Chromatography
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Abstract

An interpretation of the conditions under which there is a likeness between chromatography and the Craig method during the processing of a multicomponent mixture is given. Equations for calculating the height equivalent to a theoretical separation step are discussed. Using the results from theoretical studies, the chromatographic system is described as a multistep cascade, and the generalized thermodynamic separation theory for binary and multicomponent mixtures is extended to elution chromatography.

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References

  1. A. M. Rozen, Theory of Isotope Separation in Columns (Atomizdat, Moscow, 1960) [in Russian].

    Google Scholar 

  2. G. G. Devyatykh and Yu. E. Elliev, Introduction to the Theory of Fine Purification of Compounds (Nauka, Moscow, 1981) [in Russian].

    Google Scholar 

  3. B. M. Andreev, Ya. D. Zel’venskii, and S. G. Katal’nikov, Separation of Stable Isotopes by Physicochemical Methods (Energoatomizdat, Moscow, 1982) [in Russian].

    Google Scholar 

  4. V. M. Popov, A. D. Gerasimov, E. P. Filippov, and R. K. Pervushina, in Methods of Production and Analysis of High Purity Substances (Nauka, Moscow, 1970), p. 21 [in Russian].

    Google Scholar 

  5. V. P. Chizhkov, Russ. Chem. Rev. 40, 89 (1971).

    Article  Google Scholar 

  6. V. P. Chizhkov, Teor. Osn. Khim. Tekhnol. 3, 518 (1969).

    Google Scholar 

  7. V. P. Chizhkov, E. A. Varivonchik, Yu. V. Goryachko, et al., Zh. Fiz. Khim. 65, 1 (1991).

    CAS  Google Scholar 

  8. V. P. Chizhkov, N. V. Sterkhov, and M. P. Zabokritskii, Zh. Fiz. Khim. 65, 1729 (1991).

    Google Scholar 

  9. V. P. Chizhkov and N. V. Sterkhov, Russ. J. Phys. Chem. A 75, 1886 (2001).

    Google Scholar 

  10. V. P. Chizhkov and N. V. Sterkhov, Russ. J. Phys. Chem. A 77, 1160 (2003).

    Google Scholar 

  11. V. P. Chizhkov, N. V. Sterkhov, and V. N. Boitsov, Russ. J. Phys. Chem. A 78, 94 (2004).

    Google Scholar 

  12. R. Treybal, Liquid Extraction (McGraw-Hill, New York, 1951; Khimiya, Moscow, 1966), p. 404.

    Google Scholar 

  13. D. Peters, J. M. Hayes, and G. M. Hieftje, Chemical Separation and Measurement. Theory and Practice of Analytical Chemistry, Saunders golden series (Saunders, 1974; Khimiya, Moscow, 1978), Vol. 2, p. 504.

    Google Scholar 

  14. A. A. Zhukhovitskii and N. M. Turkel’taub, Gas Chromatography (Gostoptekhizdat, Moscow, 1962) [in Russian].

    Google Scholar 

  15. Guide on Gas Chromatography, Ed. by E. Leibnitz and H. G. Struppe (Akad. Verlag, Leipzig, 1966; Mir, Moscow, 1988), Vol. 1, pp. 10, 60.

    Google Scholar 

  16. Isotopes: Properties, Production, Application, Ed. by V. Yu. Baranov (IzdAT, Moscow, 2000) [in Russian].

    Google Scholar 

  17. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 87, 497 (2013).

    Article  CAS  Google Scholar 

  18. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 88, 138 (2014).

    Article  CAS  Google Scholar 

  19. G. Guiochon and C. L. Guillemin, Quantitative Gas Chromatography for Laboratory Analyses and On-line Process Control (Elsevier, Amsterdam, 1988), Vol. 1, pp. 16, 30.

    Google Scholar 

  20. V. P. Chizhkov, V. N. Boitsov, and A. V. Demin, Russ. J. Phys. Chem. A 85, 306 (2011).

    Article  CAS  Google Scholar 

  21. G. A. Sulaberidze and V. D. Borisevich, Russ. J. Phys. Chem. A 82, 1239 (2008).

    Article  CAS  Google Scholar 

  22. V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 80, 776 (2006).

    Article  CAS  Google Scholar 

  23. M. A. Khan, Nature 186, 810 (1960).

    Article  Google Scholar 

  24. M. A. Kan, in Proceedings of the 3rd International Symposium on Gas Chromatography, Edinburgh (Mir, Moscow, 1964), p. 214.

    Google Scholar 

  25. Liquid Column Chromatography, Ed. by H. Deyl, K. Macek, and J. Janak (Elsevier, Amsterdam, 1975; Mir, Moscow, 1978), Vol. 1, p. 48.

    Google Scholar 

  26. S. G. Perry, R. Amos, and P. I. Brewer, Practical Liquid Chromatography (Plenum, New York, 1972), p. 36.

    Book  Google Scholar 

  27. A. Adamson, The Physical Chemistry of Surfaces (Wiley, New York, 1976), p. 436.

    Google Scholar 

  28. O. Dimroth, Angew. Chem. 46, 571 (1933).

    Article  CAS  Google Scholar 

  29. E. I. Klabunovskii, Stereospecific Catalysis (Nauka, Moscow, 1968), p. 234 [in Russian].

    Google Scholar 

  30. S. D. Nogare and R. S. Juvet, Jr., Gas-Liquid Chromatography (Interscience, New York, 1962), pp. 116, 119.

    Google Scholar 

  31. S. I. Kuznetsov, V. A. Sokolov, and V. K. Sedin, in Separation and Analysis of Hydrocarbon Gases (Akad. Nauk SSSR, Moscow, 1963), p. 114 [in Russian].

    Google Scholar 

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Correspondence to V. N. Boitsov.

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Original Russian Text © V.P. Chizhkov, V.N. Boitsov, 2014, published in Zhurnal Fizicheskoi Khimii, 2014, Vol. 88, No. 9, pp. 1438–1441.

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Chizhkov, V.P., Boitsov, V.N. Multistep elution chromatography model of a multicomponent mixture. Russ. J. Phys. Chem. 88, 1605–1608 (2014). https://doi.org/10.1134/S003602441409009X

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  • DOI: https://doi.org/10.1134/S003602441409009X

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