Abstract
An interpretation of the conditions under which there is a likeness between chromatography and the Craig method during the processing of a multicomponent mixture is given. Equations for calculating the height equivalent to a theoretical separation step are discussed. Using the results from theoretical studies, the chromatographic system is described as a multistep cascade, and the generalized thermodynamic separation theory for binary and multicomponent mixtures is extended to elution chromatography.
Similar content being viewed by others
References
A. M. Rozen, Theory of Isotope Separation in Columns (Atomizdat, Moscow, 1960) [in Russian].
G. G. Devyatykh and Yu. E. Elliev, Introduction to the Theory of Fine Purification of Compounds (Nauka, Moscow, 1981) [in Russian].
B. M. Andreev, Ya. D. Zel’venskii, and S. G. Katal’nikov, Separation of Stable Isotopes by Physicochemical Methods (Energoatomizdat, Moscow, 1982) [in Russian].
V. M. Popov, A. D. Gerasimov, E. P. Filippov, and R. K. Pervushina, in Methods of Production and Analysis of High Purity Substances (Nauka, Moscow, 1970), p. 21 [in Russian].
V. P. Chizhkov, Russ. Chem. Rev. 40, 89 (1971).
V. P. Chizhkov, Teor. Osn. Khim. Tekhnol. 3, 518 (1969).
V. P. Chizhkov, E. A. Varivonchik, Yu. V. Goryachko, et al., Zh. Fiz. Khim. 65, 1 (1991).
V. P. Chizhkov, N. V. Sterkhov, and M. P. Zabokritskii, Zh. Fiz. Khim. 65, 1729 (1991).
V. P. Chizhkov and N. V. Sterkhov, Russ. J. Phys. Chem. A 75, 1886 (2001).
V. P. Chizhkov and N. V. Sterkhov, Russ. J. Phys. Chem. A 77, 1160 (2003).
V. P. Chizhkov, N. V. Sterkhov, and V. N. Boitsov, Russ. J. Phys. Chem. A 78, 94 (2004).
R. Treybal, Liquid Extraction (McGraw-Hill, New York, 1951; Khimiya, Moscow, 1966), p. 404.
D. Peters, J. M. Hayes, and G. M. Hieftje, Chemical Separation and Measurement. Theory and Practice of Analytical Chemistry, Saunders golden series (Saunders, 1974; Khimiya, Moscow, 1978), Vol. 2, p. 504.
A. A. Zhukhovitskii and N. M. Turkel’taub, Gas Chromatography (Gostoptekhizdat, Moscow, 1962) [in Russian].
Guide on Gas Chromatography, Ed. by E. Leibnitz and H. G. Struppe (Akad. Verlag, Leipzig, 1966; Mir, Moscow, 1988), Vol. 1, pp. 10, 60.
Isotopes: Properties, Production, Application, Ed. by V. Yu. Baranov (IzdAT, Moscow, 2000) [in Russian].
V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 87, 497 (2013).
V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 88, 138 (2014).
G. Guiochon and C. L. Guillemin, Quantitative Gas Chromatography for Laboratory Analyses and On-line Process Control (Elsevier, Amsterdam, 1988), Vol. 1, pp. 16, 30.
V. P. Chizhkov, V. N. Boitsov, and A. V. Demin, Russ. J. Phys. Chem. A 85, 306 (2011).
G. A. Sulaberidze and V. D. Borisevich, Russ. J. Phys. Chem. A 82, 1239 (2008).
V. P. Chizhkov and V. N. Boitsov, Russ. J. Phys. Chem. A 80, 776 (2006).
M. A. Khan, Nature 186, 810 (1960).
M. A. Kan, in Proceedings of the 3rd International Symposium on Gas Chromatography, Edinburgh (Mir, Moscow, 1964), p. 214.
Liquid Column Chromatography, Ed. by H. Deyl, K. Macek, and J. Janak (Elsevier, Amsterdam, 1975; Mir, Moscow, 1978), Vol. 1, p. 48.
S. G. Perry, R. Amos, and P. I. Brewer, Practical Liquid Chromatography (Plenum, New York, 1972), p. 36.
A. Adamson, The Physical Chemistry of Surfaces (Wiley, New York, 1976), p. 436.
O. Dimroth, Angew. Chem. 46, 571 (1933).
E. I. Klabunovskii, Stereospecific Catalysis (Nauka, Moscow, 1968), p. 234 [in Russian].
S. D. Nogare and R. S. Juvet, Jr., Gas-Liquid Chromatography (Interscience, New York, 1962), pp. 116, 119.
S. I. Kuznetsov, V. A. Sokolov, and V. K. Sedin, in Separation and Analysis of Hydrocarbon Gases (Akad. Nauk SSSR, Moscow, 1963), p. 114 [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.P. Chizhkov, V.N. Boitsov, 2014, published in Zhurnal Fizicheskoi Khimii, 2014, Vol. 88, No. 9, pp. 1438–1441.
Rights and permissions
About this article
Cite this article
Chizhkov, V.P., Boitsov, V.N. Multistep elution chromatography model of a multicomponent mixture. Russ. J. Phys. Chem. 88, 1605–1608 (2014). https://doi.org/10.1134/S003602441409009X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S003602441409009X