Skip to main content
SpringerLink
Log in

Water dimer dipole moment

  • Colloid Chemistry and Electrochemistry
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The peculiar properties of the behavior of effective polarizability of water molecules in its saturated vapor are discussed on the basis of the experimental data on the static dielectric constant. It is taken into account that in the region 273 K < T < 485 K there is a mixture of monomers and dimers in the water vapor. The comparison of the theoretical and experimental expressions for the effective polarizability shows that the dipole moment of water dimer is connected with the dipole moment of monomer via relation: d D = √2d m. The relative value of the irreducible pair contributions to the polarizability of the dimer is determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. H. Stillinger and C. W. David, J. Chem. Phys. 69, 1473 (1978).

    Article  CAS  Google Scholar 

  2. H. Umeyama and K. Morokuma, J. Am. Chem. Soc. 99, 1316 (1977).

    Article  CAS  Google Scholar 

  3. M. Schütz, S. Brdarski, P.-O. Widmark, et al., J. Chem. Phys. 107, 4597 (1997).

    Article  Google Scholar 

  4. O. Matsuoka, E. Clementi, and M. Yoshimine, J. Chem. Phys. 64, 1351 (1976).

    Article  CAS  Google Scholar 

  5. K. B. Lipkowitz and D. B. Boyd, Reviews in Computational Chemistry (Wiley-VCH, New York, 1999).

    Book  Google Scholar 

  6. H. Yu and W. F. Gunsteren, J. Chem. Phys. 121, 9549 (2004).

    Article  CAS  Google Scholar 

  7. P. L. Silvestrelli and M. Parrinello, J. Chem. Phys. 111, 3572 (1999).

    Article  CAS  Google Scholar 

  8. J. Odutola and T. R. Dyke, J. Chem. Phys. 72, 5062 (1980).

    Article  CAS  Google Scholar 

  9. Yu. M. Kessler and V. E. Petrenko, The Water: Structure, State, Solvation, Ed. by A. M. Kutepov (Nauka, Moscow, 2003) [in Russian].

  10. H. Yu and W. F. van Gunsteren, J. Chem. Phys. 121, 9549 (2004).

    Article  CAS  Google Scholar 

  11. P. T. Kiss and A. Baranyai, J. Chem. Phys. 131, 204310 (2009).

    Article  Google Scholar 

  12. T. K. Ghanty and S. K. Ghosh, J. Phys. Chem. A 106, 4200 (2002).

    Article  CAS  Google Scholar 

  13. Xu Xin and W. A. Goddard, J. Phys. Chem. A 108, 2305 (2004).

    Article  Google Scholar 

  14. H. Fröhlich, Theory of Dielectrics: Dielectric Constant and Dielectric Loss (Clarendon, Oxford, 1958).

    Google Scholar 

  15. D. Eisenberg and V. Kautsman, Structure and Properties of Water (Gidrometeoizdat, Leningrad, 1975) [in Russian].

    Google Scholar 

  16. V. L. Kulinskii, N. P. Malomuzh, and O. I. Matvejchuk, Phys. A 388, 4560 (2009).

    Article  CAS  Google Scholar 

  17. Y. Scribano, Nir Goldman, R. J. Saykally, et al., J. Phys. Chem. A 110, 5411 (2006).

    Article  CAS  Google Scholar 

  18. A. A. Vigasin, J. Quantum Spectrosc. Rad. Transfer 64, 25 (2000).

    Article  CAS  Google Scholar 

  19. M. Yu. Tretyakov, E. A. Serov, M. A. Koshelev, et al., Phys. Rev. Lett. 110, 093001 (2013).

    Article  Google Scholar 

  20. A. A. Vigasin, A. I. Pavlyuchko, Y. Jin, and S. Ikawa, J. Mol. Struct. 742, 173 (2005).

    Article  CAS  Google Scholar 

  21. N. P. Malomuzh, V. N. Makhlaichuk, P. V. Makhlaichuk, and K. N. Pankratov, J. Struct. Chem. 54, S205 (2013).

    Article  Google Scholar 

  22. A. D. Chistyakov, Russ. J. Phys. Chem. A 81, 5 (2007).

    Article  CAS  Google Scholar 

  23. P. Fernandez Diego, Y. Mulev, A. R. H. Goodwin, et al., J. Phys. Chem. Ref. Data 24(1) (1995).

    Google Scholar 

  24. M. Uematsy and E. U. Frank, J. Phys. Chem. Ref. Data 9(4) (1980).

    Google Scholar 

  25. G. E. Ashwell, P. A. Eggett, R. Emery, et al., Nature 247, 196 (1974).

    Article  CAS  Google Scholar 

  26. R. A. Bohlander, H. A. Gebbie, and G. W. F. Pardoe, Nature 228, 156 (1970).

    Article  CAS  Google Scholar 

  27. J. Hargrove, Atmos. Chem. Phys. Discuss 7, 11123 (2007).

    Article  Google Scholar 

  28. A. J. L. Shillings, S. M. Ball, M. J. Barber, et al., Atmos. Chem. Phys. 11, 4273 (2011).

    Article  CAS  Google Scholar 

  29. L. A. Curtiss, D. J. Frurip, and M. Blander, J. Chem. Phys. 71, 2703 (1979).

    Article  CAS  Google Scholar 

  30. G. T. Evans and V. Vaida, J. Chem. Phys. 113, 6652 (2000).

    Article  CAS  Google Scholar 

  31. A. H. Harvey and E. W. Lemmon, J. Phys. Chem. Ref. Data 33, 369 (2004).

    Article  CAS  Google Scholar 

  32. G. N. I. Clark, D. C. Christopher, R. J. Saykally, et al., Mol. Phys. 108, 1415 (2010).

    Article  CAS  Google Scholar 

  33. N. P. Malomuzh, V. N. Makhlaichuk, and S. V. Khrapatyi, Zh. Fiz. Khim. 88(8), 1287 (2014).

    Google Scholar 

  34. P. V. Makhlaichuk, M. P. Malomuzh, and I. V. Zhyganiuk, Ukr. J. Phys. 57, 1113 (2012).

    Google Scholar 

  35. W. L. Jorgensen, J. Am. Chem. Soc. 103, 335 (1981).

    Article  CAS  Google Scholar 

  36. H. J. C. Berendsen, J. P. M. Postma, W. F. van Gunsteren, et al., Intermolecular Forces, Ed. by B. Pullman (Reidel, Dordrecht, 1981).

  37. Wang Lu, Jijun Zhao, and Haiping Fang, J. Phys. Chem. C 112, 11779 (2008).

    Article  Google Scholar 

  38. J. Kim, S. B. Suh, and K. S. Kim, J. Chem. Phys. 111, 10077 (1999).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Mechnikov National University, Odessa, 65000, Ukraine

    N. P. Malomuzh & V. N. Makhlaichuk

  2. Taras Shevchenko National University, Kyiv, 01601, Ukraine

    S. V. Khrapatyi

Authors
  1. N. P. Malomuzh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. N. Makhlaichuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Khrapatyi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. P. Malomuzh.

Additional information

Original Russian Text © N.P. Malomuzh, V.N. Makhlaichuk, S.V. Khrapatyi, 2014, published in Zhurnal Fizicheskoi Khimii, 2014, Vol. 88, Nos. 7–8, pp. 1251–1256.

The article was translated by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Malomuzh, N.P., Makhlaichuk, V.N. & Khrapatyi, S.V. Water dimer dipole moment. Russ. J. Phys. Chem. 88, 1431–1435 (2014). https://doi.org/10.1134/S0036024414080172

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024414080172

Keywords

Search

Navigation