Skip to main content
Log in

Powder diffraction data and mesomorphic properties of 4-butyloxyphenyl 4′-decyloxybenzoate

  • Structure of Matter and Quantum Chemistry
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Unit cell parameters calculated from X-ray powder diffraction data are presented for the crystalline phase of a liquid crystal 4-butyloxyphenyl 4′-decyloxybenzoate: a = 23.098 (4) Å, b = 5.974 (6) Å, c = 12.357 (10) Å, β = 121.5283 (788)°, unit-cell volume V = 1453.56 Å3. Temperature dependent X-ray diffraction data confirmed the existence of smectic A and smectic C mesophases and a more ordered, tilted crystalline smectic phase. Possibility of existence of previously reported smectic B phase as well as another crystalline phase was refuted.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W. den Boer, Active Matrix Liquid Crystal Displays: Fundamentals and Applications (Elsevier Science, 2011).

    Google Scholar 

  2. S. T. Lagerwall, Ferroelectric and Antiferroelectric Liquid Crystals (Wiley, 2008).

    Google Scholar 

  3. A. Bubnov, V. Hamplová, M. Kašpar, et al., J. Therm. Anal. Calorim. 90, 431 (2007).

    Article  CAS  Google Scholar 

  4. D. Ž. Obadović, M. Stojanović, M. Cvetinov, et al., Russ. J. Phys. Chem. A 85, 2354 (2011).

    Article  Google Scholar 

  5. L. Dobiášová, H. Šíchová, and V. Valvoda, Powder Diffract. 18, 293 (2003).

    Article  Google Scholar 

  6. K. Takada, T. Noma, T. Togano, et al., Powder Diffract. 19, 53 (2004).

    Article  CAS  Google Scholar 

  7. P. Lakshmi Praveen and D. Ojha, Russ. J. Phys. Chem. A 85, 1756 (2011).

    Article  CAS  Google Scholar 

  8. T. T. Blair, M. E. Neubert, M. Tsai, et al., J. Phys. Chem. Ref. Data 20, 189 (1991).

    Article  CAS  Google Scholar 

  9. R. K. Bamezai, A. Soni, Z. Vakhovskaya, et al., Russ. J. Phys. Chem. A 83, 2283 (2009).

    Article  CAS  Google Scholar 

  10. L. A. Nosikova, Z. A. Kudryashova, L. D. Iskhakova, et al., Russ. J. Phys. Chem. A 81, 1263 (2007).

    Article  CAS  Google Scholar 

  11. D. Y. Yoon, N. Masciocchi, L. E. Depero, et al., Macromolecules 23, 1793 (1990).

    Article  CAS  Google Scholar 

  12. J. Liu, B. L. Yuan, P. H. Geil, et al., Polymer 38, 6031 (1997).

    Article  CAS  Google Scholar 

  13. I. I. Konstantinov, E. K. Lermontova, and L. G. Kuz’mina, Crystallogr. Rep. 56, 128 (2011).

    Article  CAS  Google Scholar 

  14. D. F. Aliev and H. F. Abbasov, Mol. Cryst. Liq. Cryst. Incorp. Nonlinear Opt. 151, 345 (1987).

    Article  CAS  Google Scholar 

  15. D. Demus, H. Demus, and H. Zaschke, Flüssige Kristalle in Tabellen (Deutscher Verlag für Grundstoffindustrie, 1976).

    Google Scholar 

  16. G. B. Rocha, R. O. Freire, A. M. Simas, et al., J. Comput. Chem. 27, 1101 (2006).

    Article  CAS  Google Scholar 

  17. R. W. Cheary and A. A. Coelho, Engineering and Physical Sciences Research Council (Daresbury Laboratory, Warrington, England, 1996).

    Google Scholar 

  18. P.-E. Werner, L. Eriksson, and M. Westdahl, J. Appl. Crystallogr. 18, 367 (1985).

    Article  CAS  Google Scholar 

  19. R. Shirley, The CRYSFIRE System for Automatic Powder Indexing: User’s Manual (The Lattice Press, 2000).

    Google Scholar 

  20. G. S. Smith and R. L. Snyder, J. Appl. Crystallogr. 12, 60 (1979).

    Article  CAS  Google Scholar 

  21. P. M. de Wolff, J. Appl. Crystallogr. 1, 108 (1968).

    Article  Google Scholar 

  22. M. Stojanović, A. Bubnov, D. Ž. Obadović, et al., Phase Trans. 84, 380 (2011).

    Article  Google Scholar 

  23. D. Ž. Obadović, M. Stojanović, S. Jovanović-Šanta, et al., Mol. Cryst. Liq. Cryst. 547, 46/1736 (2011).

    Google Scholar 

  24. D. Demus, J. W. Goodby, G. W. Gray, et al., Handbook of Liquid Crystals, in 4 vols. (Wiley, 1998).

    Book  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Cvetinov.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Cvetinov, M., Stojanović, M., Obadović, D. et al. Powder diffraction data and mesomorphic properties of 4-butyloxyphenyl 4′-decyloxybenzoate. Russ. J. Phys. Chem. 88, 1142–1146 (2014). https://doi.org/10.1134/S0036024414070115

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024414070115

Keywords

Navigation