Abstract
Samples are obtained via the thermolysis of binary complex compounds in a hydrogen atmosphere. Their catalytic activity in hydrogen peroxide decomposition is studied. The values of the rate constants and activation energies for the catalytic reaction are estimated. The correlation between catalytic activity, composition, specific surface area (S sp), and particle size of the samples is analyzed.
Similar content being viewed by others
References
V. N. Parmon, A. S. Noskov, N. P. Anfimova, and V. P. Shmachkova, Katal. Promyshl., No. 1, 6 (2006).
D. J. Duvenhage and N. J. Coville, Appl. Catal. A: Gen. 289, 231 (2005).
L. P. Oleksenko and L. V. Lutsenko, Russ. J. Phys. Chem. A 87, 180 (2013).
M. D. Navalikhina, N. E. Kavalerskaya, E. S. Lokteva, et al., Russ. J. Phys. Chem. A 86, 1669 (2012).
Y. Takita, Y. Sadatomi, H. Nishigushi, and K. Nagaoka, Bull. Chem. Soc. Jpn. 79, 145 (2006).
S. V. Korenev, A. B. Venediktov, Yu. V. Shubin, et al., Zh. Strukt. Khim. 44(1), 58 (2003).
E. M. Churakova, S. D. Badmaev, P. V. Snytnikov, et al., Kinet. Catal. 51, 893 (2010).
B. G. Ershov, A. V. Anan’ev, E. V. Abkhalimov, et al., Ros. Nanotekhnol., Nos. 5–6, 79 (2011).
J. de Laat and H. Gallard, Environ. Sci. Technol. 33, 2726 (1999).
J. Deren, J. Haber, A. Podgorecka, and J. Burzyk, J. Catal. 2, 161 (1963).
Shu-Sung Lin and M. D. Gurol, Environ. Sci. Technol. 32, 1417 (1998).
H. Zhou, Y. F. Shen, J. Y. Wang, X. Chen, et al., J. Catal. 176, 321 (1998).
M. A. Hasan, M. L. Zaki, L. Pasapulety, and K. Kumari, Appl. Catal. A: Gen. 181, 171 (1999).
Si-Hyun Do, Bill Batchelor, Hong-Kyun Lee, and Sung-Ho Kong, Chemosphere 75, 8 (2009).
L. C. A. Oliveira, T. C. Ramalho, E. F. Souza, et al., Appl. Catal. B: Environ. 83, 169 (2008).
S. I. Pechenyuk, D. P. Domonov, D. L. Rogachev, and A. T. Belyaevskii, Russ. J. Inorg. Chem. 52, 1027 (2007).
S. I. Pechenyuk, D. P. Domonov, and A. T. Belyaevskii, Russ. J. Inorg. Chem. 53, 1221 (2008).
S. I. Pechenyuk, D. P. Domonov, A. N. Gosteva, et al., Izv. SPb. Tekh. Inst., No. 15 (41), 18 (2012).
S. I. Pechenyuk, D. P. Domonov, A. N. Gosteva, et al., Russ. J. Coord. Chem. 38, 596 (2012).
S. I. Pechenyuk, A. N. Gosteva, D. P. Domonov, and T. I. Makarova, Vestn. Yuzhno-Ural. Gos. Univ., Ser. Khim., No. 3, 4 (2012).
JCPDS-JCDD Data Base (2002).
G. Charlot, Les méthodes de la chimie analytique: Analyse quantitative minérale (Masson, Paris, 1961).
D. P. Domonov, Candidate’s Dissertation in Chemistry (Novosibirsk, 2009).
Yu. G. Frolov, Manual of Colloid Chemistry: Surface Phenomena and Disperse Systems (Khimiya, Moscow, 1989) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © D.P. Domonov, S.I. Pechenyuk, A.N. Gosteva, 2014, published in Zhurnal Fizicheskoi Khimii, 2014, Vol. 88, No. 6, pp. 926–931.
Rights and permissions
About this article
Cite this article
Domonov, D.P., Pechenyuk, S.I. & Gosteva, A.N. Products of binary complex compounds thermolysis: Catalysts for hydrogen peroxide decomposition. Russ. J. Phys. Chem. 88, 913–918 (2014). https://doi.org/10.1134/S0036024414060119
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024414060119