Abstract
Interaction of rare-earth oxides (Pr, Tb, Er) with periodic acid or sodium iodate under hydrothermal conditions in the presence of Na2HPO4⋅12H2O leads to formation of complex NaLn(IO3)4 iodates. The compounds of Pr and Tb are reported for the first time. Single-crystal studies reveal that they are isostructural to the previously reported analogs of other rare-earths and adopt the non-centrosymmetric space group Сс. Polycrystalline samples generate a strong SHG signal above that of the potassium dihydrogen phosphate reference standard. They also exhibit wide optical transparency areas and high thermal stability.
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ACKNOWLEDGMENTS
The authors thank T.B. Shatalova and A.F. Murtazoev for the help in conducting the experiments.
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Tis work was financially supported by the Russian Foundation for Basic Research, grant no. 20-03-00702А.
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Grigorieva, O.P., Stefanovich, S.Y., Charkin, D.O. et al. NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure. Russ. J. Inorg. Chem. 68, 1516–1522 (2023). https://doi.org/10.1134/S0036023623601976
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DOI: https://doi.org/10.1134/S0036023623601976