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Revisiting the Thermodynamic Characteristics of Titanium Fluorides

  • PHYSICAL METHODS OF INVESTIGATION
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Abstract

New values for the standard enthalpies of formation of titanium fluorides at 0 K have been obtained by revisiting data on homogeneous and heterogeneous equilibria with their participation (kJ/mol): –1403.2 ± 2.7 for TiF3(c), –1144.2 ± 3.3 for TiF3, –2349.4 ± 6.3 for Ti2F5(c); –933.7 ± 6.8 for TiF2(c), and –650.4 ± 2.4 TiF2. The thermodynamic metastability of TiF2(c) has been shown.

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Funding

The work was carried out within the framework of the State assignment of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences in the field of basic research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. I. Nikitin & A. S. Alikhanyan

  2. Joint Institute of High Temperatures, 125412, Moscow, Russia

    E. L. Osina

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  1. M. I. Nikitin
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  2. E. L. Osina
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  3. A. S. Alikhanyan
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Correspondence to A. S. Alikhanyan.

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Translated by G. Kirakosyan

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Nikitin, M.I., Osina, E.L. & Alikhanyan, A.S. Revisiting the Thermodynamic Characteristics of Titanium Fluorides. Russ. J. Inorg. Chem. 68, 278–286 (2023). https://doi.org/10.1134/S003602362260280X

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  • DOI: https://doi.org/10.1134/S003602362260280X

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