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Room Temperature Synthesis, Crystal Structure, Hirshfeld Surface Analysis, and Fluorescence Properties of One Novel Cubane Zinc Cluster Based on 1-{2-Hydroxy-3-[(2-Hydroxy-3-Methoxy-Benzylidene)-Amino]-Phenyl}-Ethanone

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Abstract—

One novel distorted cubane zinc cluster, [Zn4(L)4]·(DMF)2 (1, H2L = 1-{2-Hydroxy-3-[(2- hydroxy-3-methoxy-benzylidene)-amino]-phenyl}-ethanone, DMF = N,N'-dimethyl-formamide), was obtained by room temperature synthesis. The cluster was characterized using elemental analysis, powder X‑ray diffraction, IR spectroscopy, and single-crystal X-ray diffraction. 1 is a cubane zinc cluster. The L ligand of 1 displays two different coordination modes: One is the μ3-L-κ6O1,N1,O2:O2:O2,O3 and the other is μ2-L-κ5O1,O2:O2,N1,O3 coordination modes. Hirshfeld surface analysis revealed that H···H interaction was the most abundant intermolecular interaction. The cluster emits a red fluorescence of 622 at 517 nm excite.

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Funding

This work was supported by the National Natural Science Foundation of China (contract no. 21861014) and Talent Introduction Project of Guangdong University of Petrochemical Technology (no. 2020rc033).

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Authors and Affiliations

  1. Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials (College of Chemistry and Bioengineering), Guilin University of Technology, 541004, Guilin, China

    Tao Zhou, Haiyang Zhang, Shu-Hua Zhang & Zhenguang Hu

  2. College of Chemistry, Guangdong University of Petrochemical Technology, Maoming, 525000, Guangdong, China

    Tao Zhou & Shu-Hua Zhang

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  1. Tao Zhou
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Tao Zhou, Zhang, H., Zhang, SH. et al. Room Temperature Synthesis, Crystal Structure, Hirshfeld Surface Analysis, and Fluorescence Properties of One Novel Cubane Zinc Cluster Based on 1-{2-Hydroxy-3-[(2-Hydroxy-3-Methoxy-Benzylidene)-Amino]-Phenyl}-Ethanone. Russ. J. Inorg. Chem. 67 (Suppl 1), S35–S41 (2022). https://doi.org/10.1134/S0036023622601817

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