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A 3D Zn(II) Metal-Organic Framework Based on Citraconic Acid and 1,2-Bi(4-pyridyl)ethylene Mixed Ligands: Crystal Structure, Luminescence, and [2+2] Cycloaddition Reaction

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Abstract

A Zn(II) coordination polymer, {[Zn(ca)(bpe)]·0.5H2O}n (H2ca = citraconic acid, bpe = 1,2-bi(4-pyridyl)ethylene) has been prepared by hydrothermal reaction, and characterized by single-crystal X-ray diffraction, elemental analysis, FT IR, PXRD, and TGA. Title compound exhibits a three-dimensional metal-organic framework with lvt topology type and 42⋅84 Schläfli symbol. The compound has good phase purity and high thermal stability. The emission spectrum of the complex is similar to that of the powdered free bpe molecule, but the obvious red-shift may be due to the coordination of bpe with Zn ions, resulting in a reduced nonradiative decay of the intraligand excited state. The center-to-center olefin bond distance of bpe ligand in the compound, 3.620 Å, is suitable to undergo [2+2] cycloaddition reaction. The 1H NMR spectrum of the cycloaddition product after UV irradiation for 24 h shows that the double bonds were partially photodimerized (82.6%) into the rctt-tpcb and rtct-tpcb derivatives.

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REFERENCES

  1. S. Kitagawa and K. Uemera, Chem. Soc. Rev. 34, 109 (2005). https://doi.org/10.1039/B313997M

    Article  CAS  PubMed  Google Scholar 

  2. S. M. Oburn, D. C. Swenson, S. V. S. Mariappan, et al., J. Am. Chem. Soc. 139, 8452 (2017). https://doi.org/10.1021/jacs.7b04420

    Article  CAS  PubMed  Google Scholar 

  3. K. M. Hutchins, J. C. Sumrak, and L. R. MacGillivray, Org. Lett. 16, 1052 (2014). https://dx,doi.org/https://doi.org/10.1021/ol4035403

  4. R. Medishetty, I. H. Park, S. S. Lee, et al., Chem. Commun. 52, 3989 (2016). https://doi.org/10.1002/chin.201616208

    Article  CAS  Google Scholar 

  5. R. Medishetty, R. Tandiana, L. L. Koh, et al., Chem. Eur. J. 20, 1231 (2014). https://doi.org/10.1002/chem.201304246

    Article  CAS  PubMed  Google Scholar 

  6. M. M. Gan, J. G. Yu, Y. Y. Wang, et al., Cryst. Growth Des. 18, 553 (2018). https://doi.org/10.1021/acs.cgd.7b01308

    Article  CAS  Google Scholar 

  7. W. J. Gong, Z. G. Ren, H. X. Li, et al., Cryst. Growth Des. 17, 870 (2017). https://doi.org/10.1021/acs.cgd.6b01728

    Article  CAS  Google Scholar 

  8. F. L. Hu, Y. Mi, C. Zhu, et al., Angew. Chem. Int. Ed. 57, 12696 (2018). https://doi.org/10.1002/anie.201806076

    Article  CAS  Google Scholar 

  9. T. D. Hamilton, G. S. Papaefstathiou, L. R. MacGillivray, J. Am. Chem. Soc. 124, 11606 (2002). https://doi.org/10.1021/ja0278281

    Article  CAS  PubMed  Google Scholar 

  10. M. Nagarathinam and J. J. Vittal, Chem. Commun. 438 (2008). https://doi.org/10.1039/b713586f

  11. G. S. Papaefstathiou, I. G. Georgiev, T. Friščić, et al., Chem. Commun. 3974 (2005). https://doi.org/10.1039/b504477d

  12. M. H. Mir, L. L. Koh, G. K.Tan, et al., Angew. Chem. Int. Ed. 49, 390 (2010). https://doi.org/10.1002/anie.200905898

    Article  CAS  Google Scholar 

  13. G. S. Papaefstathiou, Z. M. Zhong, L. Geng, et al., J. Am. Chem. Soc. 126, 9158 (2004). https://doi.org/10.1021/ja047819n

    Article  CAS  PubMed  Google Scholar 

  14. G. L. Li, W. D. Yin, G. Z. Liu, et al., Inorg. Chem. Commun. 43, 165 (2014). https://doi.org/10.1016/j.inoche.2014.02.037

    Article  CAS  Google Scholar 

  15. A. M. P. Peedikakkal, L. L. Koh, J. J. Vittal, Chem. Commun. 441 (2008). https://doi.org/10.1039/b714355a

  16. G. L. Li, G. Z. Liu, L. F. Ma, et al., Chem. Commun. 50, 2615 (2014). https://doi.org/10.1039/c3cc49106d

    Article  CAS  Google Scholar 

  17. R. Medishetty, R. Tandiana, J. Wu, et al., Chem. Eur. J. 21, 11948 (2015). https://doi.org/10.1002/chem.201501649

    Article  CAS  PubMed  Google Scholar 

  18. S. Y. Yang, X. L. Deng, R. F. Jin, et al., J. Am. Chem. Soc. 136, 558 (2014). https://doi.org/10.1021/ja409272p

    Article  CAS  PubMed  Google Scholar 

  19. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr. 42, 339 (2009). https://doi.org/10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  20. G. M. Sheldrick, Acta Crystallogr. A71, 3 (2015). https://doi.org/10.1107/S2053273314026370

    Article  CAS  Google Scholar 

  21. G. M. Sheldrick, Acta Crystallogr. C71, 3 (2015). https://doi.org/10.1107/S2053229614024218

    Article  CAS  Google Scholar 

  22. S. E. Korolenko, V. V. Avdeeva, E. A. Malinina, et al., Russ. J. Inorg. Chem. 66, 1350 (2021). https://doi.org/10.1134/S0036023621090047

    Article  CAS  Google Scholar 

  23. M. H. Zuo, J. Zhou, J. H. Yu, et al., Russ. J. Inorg. Chem. 66, 982 (2021). https://doi.org/10.1134/S0036023621070159

    Article  Google Scholar 

  24. S. E. Korolenko, K. P. Zhuravlev, V. I. Tsaryuk, et al., J. Lumin. 237, 118156 (2021). https://doi.org/10.1016/j.jlumin.2021.118156

    Article  CAS  Google Scholar 

  25. D. Ureche, A. Rija, I. Bulhac, et al., Russ. J. Inorg. Chem. 65, 1838 (2021). https://doi.org/10.1134/S0036023620120189

    Article  Google Scholar 

  26. L. L. Li, S. S. Feng, J. Q. Zhang, et al., Russ. J. Gen. Chem. 91, 1128 (2021). https://doi.org/10.1134/S1070363221060220

    Article  CAS  Google Scholar 

  27. J. Buasakuna, P. Srilaoonga, K. Chainokb, et al., Inorg. Chim. Acta 511, 119839 (2020). https://doi.org/10.1016/j.ica.2020.119839

    Article  CAS  Google Scholar 

  28. A. Halder, B. Bhattacharya, F. Haque, et al., Cryst. Growth Des. 17, 6613 (2017). https://doi.org/10.1021/acs.cgd.7b01270

    Article  CAS  Google Scholar 

  29. G. L. Li, W. D. Yin, Q. L. Liu, et al., Chin. J. Inorg. Chem. 35, 2355 (2019). https://doi.org/10.11862/CJIC.2019.271

    Article  CAS  Google Scholar 

  30. Y. P. Li, F. Y. Ju, G. L. Li, et al., Russ. J. Coord. Chem. 44, 214 (2018). https://doi.org/10.1134/S1070328418030028

    Article  CAS  Google Scholar 

  31. J. Tao, M. L. Tong, J. X. Shi, et al., Chem. Commun. 20, 2043 (2000). https://doi.org/10.1039/B005753N

    Article  Google Scholar 

  32. L. Y. Xin, G. Z. Liu, L. F. Ma, et al., Aust. J. Chem. 68, 758 (2015). https://doi.org/10.1071/CH14347

    Article  CAS  Google Scholar 

  33. Y. C. Sun, Q. Q. Wei, Q. X. Wang, et al., Russ. J. Coord. Chem. 48, 60 (2022). https://doi.org/10.1134/S1070328422010067

    Article  CAS  Google Scholar 

  34. V. F. Shul’gin, M. A. Kiskin, A. N. Gusev, et al., Russ. J. Coord. Chem. 47, 326 (2021). https://doi.org/10.1134/S1070328421050079

    Article  Google Scholar 

  35. G. Z. Liu, S. H. Li, X. L. Li, et al., CrystEngComm 15, 4571 (2013). https://doi.org/10.1039/C3CE40109J

    Article  CAS  Google Scholar 

  36. T. Caronna, R. Liantonio, T. A. Logothetis, et al., J. Am. Chem. Soc. 126, 4500 (2004). https://doi.org/10.1021/ja039884n

    Article  CAS  PubMed  Google Scholar 

  37. L. R. MacGillivray, J. F. Reid, J. A. Ripmeester, et al., Ind. Eng. Chem. Res. 41, 4494 (2002). https://doi.org/10.1021/ie010775w

    Article  CAS  Google Scholar 

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Funding

This work was supported by the National Natural Science Foundation of China (project no. 21571093).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, 471934, Luoyang, China

    Gui-Lian Li, Jin-Yuan Zhang, Gao-Jing Du, Yu-Han Xia & Guang-Zhen Liu

  2. School of Food and Drug, Luoyang Normal University, 471934, Luoyang, China

    Wei-Dong Yin

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  1. Gui-Lian Li
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  2. Wei-Dong Yin
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Correspondence to Guang-Zhen Liu.

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Gui-Lian Li, Yin, WD., Zhang, JY. et al. A 3D Zn(II) Metal-Organic Framework Based on Citraconic Acid and 1,2-Bi(4-pyridyl)ethylene Mixed Ligands: Crystal Structure, Luminescence, and [2+2] Cycloaddition Reaction. Russ. J. Inorg. Chem. 67, 1745–1750 (2022). https://doi.org/10.1134/S0036023622600800

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