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Study of Strontium Sorption by Amorphous Calcium Silicate

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Abstract

Data on the sorption characteristics of synthetic X-ray amorphous calcium silicate obtained in the CaCl2–Na2SiO3–H2O model multicomponent system are presented. The isotherms of sorption of Sr2+ ions from aqueous solutions without supporting salt at Sr2+ concentrations of 0.016 to 1.22 mmol/L at temperatures of 20, 40 and 60°C and the solid to liquid phase ratio S : L = 1 : 400 are presented. The maximum sorption capacities of synthetic X-ray amorphous calcium silicate and the recoveries of Sr2+ ions were determined for various S : L ratios and for solutions containing no supporting salt and solutions mimicking the specific composition of fresh water. The Sr2+ sorption kinetics at various temperatures was studied for the first time; and the activation energy of sorption was determined. The results can be used to develop practical recommendations for the production of this material and application in the processes of strontium sorption and immobilization.

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ACKNOWLEDGMENTS

The analysis of solutions for the content of Sr2+ ions was performed on the equipment of the center for collective use “Far Eastern Center for Structural Research” of the Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, and partly using the equipment of the center for collective use “Primorsky Center for Local, Elemental, and Isotopic Analysis” of the Far East Geological Institute, Far Eastern Branch, Russian Academy of Sciences.

Funding

This study was performed within the framework of the state assignment of the Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, no. FWFN(0205)-2022-0002, subject 2, section 3.

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    S. B. Yarusova, P. S. Gordienko, E. A. Nekhliudova, Yu. A. Parotkina, A. N. Drankov & S. B. Bulanova

  2. Vladivostok State University of Economics and Service, 690014, Vladivostok, Russia

    S. B. Yarusova, E. A. Nekhliudova, A. V. Perfilev & N. V. Ivanenko

  3. Far Eastern Federal University, Russky Island, 690922, Vladivostok, Russia

    O. O. Shichalin & E. K. Papynov

  4. Far East Geological Institute, Far Eastern Branch, Russian Academy of Sciences, 690922, Vladivostok, Russia

    S. Yu. Budnitskiy & N. V. Zarubina

Authors
  1. S. B. Yarusova
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  2. P. S. Gordienko
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  3. O. O. Shichalin
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  4. E. K. Papynov
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  5. E. A. Nekhliudova
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  6. A. V. Perfilev
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  7. S. Yu. Budnitskiy
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  8. N. V. Zarubina
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  9. Yu. A. Parotkina
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  10. A. N. Drankov
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  11. S. B. Bulanova
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  12. N. V. Ivanenko
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Contributions

S.B. Yarusova and P.S. Gordienko invented and designed the experiment; E.A. Nekhliudova, A.V. Perfilev, and A.N. Drankov synthesized the samples; O.O. Shichalin and E.K. Papynov participated in data processing; S.Yu. Budnitskii, N.V. Zarubina, and Yu.A. Parotkina carried out studies by methods of mass spectrometry with inductively coupled plasma and atomic absorption spectrometry. S.B. Bulanova carried out theoretical calculations; N.V. Ivanenko wrote the paper. All authors discussed the results and commented on the manuscript.

Corresponding author

Correspondence to S. B. Yarusova.

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The authors declare that they have no conflicts of interest.

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Translated by Z. Svitanko

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Yarusova, S.B., Gordienko, P.S., Shichalin, O.O. et al. Study of Strontium Sorption by Amorphous Calcium Silicate. Russ. J. Inorg. Chem. 67, 1386–1392 (2022). https://doi.org/10.1134/S0036023622090194

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  • DOI: https://doi.org/10.1134/S0036023622090194

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