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Synthesis of Gold(I) Complexes with 10-(Aryl)phenoxarsines

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Abstract

A series of dimeric gold(I) complexes L2Au2Cl2 has been synthesized by the reaction of equimolar amounts of 10-(aryl)phenoxarsine ligands with chloro(tetrahydrothiophene)gold(I). The structure of complexes 4–6 has been confirmed by a combination of physicochemical methods. The crystal structure of complex 4 has been determined by single-crystal X-ray diffraction. The Tolman angles have been calculated for the known tertiary arsine ligands and the ligands in the synthesized gold complexes. It has been shown that the dimeric structure of the complexes is formed through the aurophilic interaction between two monomers. The Tolman angle of the phenoxarsine ligand plays a significant role in this interaction; in the dimeric complexes, this angle is on average 147°.

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ACKNOWLEDGMENTS

The authors acknowledge the technical support of the Collective Spectro-Analytical Center for the Study of the Structure, Composition, and Properties of Substances and Materials, Kazan Scientific Center.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 420088, Kazan, Russia

    M. F. Galimova, A. B. Dobrynin, E. I. Musina & A. A. Karasik

  2. Kazan National Research Technological University, 420015, Kazan, Russia

    R. R. Musin

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  1. M. F. Galimova
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  2. A. B. Dobrynin
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  3. E. I. Musina
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  4. R. R. Musin
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Correspondence to M. F. Galimova.

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The authors declare no conflicts of interest.

ADDITIONAL INFORMATION

The article is prepared on the materials of the XXVIII International Chugaev Conference on Coordination Chemistry, Ol’ginka, Tuapse oblast, Russia October 3–8, 2021.

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Translated by G. Kirakosyan

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Galimova, M.F., Dobrynin, A.B., Musina, E.I. et al. Synthesis of Gold(I) Complexes with 10-(Aryl)phenoxarsines. Russ. J. Inorg. Chem. 67, 1203–1210 (2022). https://doi.org/10.1134/S0036023622080125

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