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Formation of the BiAl3(PO4)2(OH)6 Compound with a Waylandite Structure under Hydrothermal Conditions

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

The BiAl3(PO4)2(OH)6 compound with a waylandite structure has been synthesized for the first time under hydrothermal conditions at 200°С and a pressure of 7 MPa. It has been shown that the compound forms through the formation of an intermediate crystalline phase—trigonal BiPO4—and an amorphous phase of composition 0.5[3Al2O3 ⋅ 2P2O5 ⋅ 6H2O]. According to SEM data, particles resembling in morphology particles of the phase with a waylandite structure are detected after 6 h of synthesis. The formation of BiAl3(PO4)2(OH)6 in amounts distinguishable by X-ray diffraction is fixed after 12 h and almost completely ends after 48 h of hydrothermal treatment of the suspension of precursors. The formation of waylandite is confirmed by SEM and IR spectroscopy. The structure of BiAl3(PO4)2(OH)6 was refined by the Rietveld method from powder X-ray diffraction data (space group \(R\bar {3}m\) (166) in hexagonal axes, unit cell parameters: a = 6.99608(5) Å, c = 16.1495(4) Å). Refinement gives the filling factors of unity within the standard deviation for the positions of atoms heavier than oxygen. The measured pycnometric density of the sample (4.01(8) g/cm3) is slightly lower than the density calculated from the results of structure refinement (4.235(2) g/cm3).

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ACKNOWLEDGMENTS

The authors are grateful to V.V. Gusarov for attention to the work and valuable comments. The equipment of the Engineering Center of St. Petersburg State Technological Institute (TU) was used in the work. The X-ray diffraction experiment was processed using the software of the Federal Joint Research Center “Materials science and characterization in advanced technology” (Ioffe Institute, St.Petersburg.

Funding

The work of D.P.E. and O.V.P. was supported by the Russian Science Foundation (project no. 21-13-00260).

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Authors and Affiliations

  1. Ioffe Physical Technical Institute, 194021, St. Petersburg, Russia

    D. P. Elovikov, M. V. Tomkovich, A. A. Levin & O. V. Proskurina

  2. St. Petersburg State Technological Institute (Technical University), 190013, St. Petersburg, Russia

    D. P. Elovikov & O. V. Proskurina

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  1. D. P. Elovikov
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  2. M. V. Tomkovich
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Correspondence to D. P. Elovikov.

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Translated by G. Kirakosyan

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Elovikov, D.P., Tomkovich, M.V., Levin, A.A. et al. Formation of the BiAl3(PO4)2(OH)6 Compound with a Waylandite Structure under Hydrothermal Conditions. Russ. J. Inorg. Chem. 67, 850–860 (2022). https://doi.org/10.1134/S0036023622060067

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