Abstract
Polycrystalline spinel ferrites of composition Li0.33Fe2.29Zn0.21Mn0.17O4 have been synthesized by the ceramic method at sintering temperatures of 950, 1000, 1050, and 1100°С. The crystal structure of the resulting samples has been studied by X-ray powder diffraction, and the chemical composition of the ferrites has been refined by the secondary ion mass spectrometry. Magnetic characteristics of the samples have been measured on an MK-3E magnetic measuring device. Room-temperature Mössbauer spectra have been recorded on an Ms-1104 Em spectrometer. The cation distribution in the crystal lattice of the resulting ferrites has been established; crystal chemical formulas have been calculated for each sintering temperature. The Mössbauer spectra of all the obtained samples are modeled by five sextets, which is explained by the appearance of nonequivalent Fe3+ ions in octahedral and tetrahedral positions, differing in the composition of the second coordination sphere. Combinations of lithium, manganese, and zinc ions in the nearest cationic environment of octahedral iron ions have been determined on the basis of a model that takes into account the peculiarities of changes in the Mössbauer parameters with an increase in the sintering temperature of ferrites. It has been shown that Mössbauer spectroscopy in combination with X-ray powder diffraction and magnetometry provides efficient control of the phase composition, cation distribution, and magnetic properties in substituted ferrites.
Similar content being viewed by others
REFERENCES
L. I. Rabkin, S. A. Soskin, and B. Sh. Epshtein, Ferrites. Structure, Properties, Production Technology (Energiya, Leningrad,1968) [in Russian].
L. M. Letyuk, V. G. Kostishin, and A. V. Gonchar, Ferrite Materials Technology of Magnetoelectronics (MISiS, Moscow, 2005) [in Russian].
F. Xie, Y. Chen, M. Bai, and P. Wang, Ceram. Int. 45, 17915 (2019). https://doi.org/10.1016/j.ceramint.2019.06.008
F. Xu, X. Shi, Y. Yang, et al., J. Alloys Compd. 827, 154338 (2020). https://doi.org/10.1016/j.jallcom.2020.154338
F. Xie, H. Liu, M. Bai, et al., Ceram. Int. 47, 1121 (2021). https://doi.org/10.1016/j.ceramint.2020.08.228
X. Wang, Y. Li, Z. Chen, et al., J. Alloys Compd. 797, 566 (2019). https://doi.org/10.1016/j.jallcom.2019.05.102
Y. Liao, Y. Wang, Z. Chen, et al., Ceram. Int. 46, 487 (2020). https://doi.org/10.1016/j.ceramint.2019.08.286
F. Xie, H. Liu, J. Zhao, et al., J. Alloys Compd. 851, 156806 (2021). https://doi.org/10.1016/j.jallcom.2020.156806
F. Xie, H. Liu, S. Zhou, et al., J. Alloys Compd. 862, 158650 (2021). https://doi.org/10.1016/j.jallcom.2021.158650
S. A. Mazen, H. M. Elsayed, and N. I. Abu-Elsaad, Mater. Chem. Phys. 256, 123676 (2020). https://doi.org/10.1016/j.matchemphys.2020.123676
V. S. Sawant, A. A. Bagade, and K. Y. Rajpure, Phys. B: Condens. Matter. 474, 47 (2015). https://doi.org/10.1016/j.physb.2015.06.005
N. Qing, S. Li, C. Ensi, et al., Curr. Appl. Phys. 20, 1019 (2020). https://doi.org/10.1016/j.cap.2020.06.012
Qing Nia, Li Suna, Ensi Cao, et al., Ceram. Int. 46, 9722 (2020). https://doi.org/10.1016/j.ceramint.2019.12.240
A. P. Surzhikov, E. V. Nikolaev, E. N. Lysenko, et al., Izv. VUZov, Fiz. 63, 164 (2020). https://doi.org/10.17223/00213411/63/5/164
Q. Zhao, H. Zhang, F. Xu, et al., J. Alloys Compd. 764, 834 (2018). https://doi.org/10.1016/j.jallcom.2018.06.080
T. Collins and A. E. Brown, J. Appl. Phys. 42, 3451 (1971). https://doi.org/10.1063/1.1660752
P. Baba, G. Argentina, and W. Courtney, IEEE Trans. Magn. 8, 83 (1972). https://doi.org/10.1109/TMAG.1972.1067269
A. N. Yusoff and M. H. Abdullah, J. Magn. Magn. Mater. 269, 271 (2004). https://doi.org/10.1016/S0304-8853(03)00617-6
T. Nakamura, T. Miyamoto, and Y. Yamada, J. Magn. Magn. Mater. 256, 340 (2003). https://doi.org/10.1016/S0304-8853(02)00698-4
D. Kim, Y. Yoon, K. Jo, et al., J. Electromagn. Eng. Sci. 16, 150 (2016). https://doi.org/10.5515/JKIEES.2016.16.3.150
V. V. Korovushkin, A. V. Trukhanov, V. G. Kostishin, et al., Russ. J. Inorg. Chem. 64, 574 (2019). https://doi.org/10.1134/S0036023619050115
V. Verma, V. Pandeya, V. N. Shukla, et al., Solid State Commun. 149, 1726 (2009). https://doi.org/10.1016/j.ssc.2009.06.010
E. N. Lysenko, A. L. Astafyev, and V. A. Vlasov, J. Magn. Magn. Mater. 465, 457 (2018). https://doi.org/10.1016/j.jmmm.2018.06.010
S. F. Marenkin, I. V. Fedorchenko, V. M. Trukhan, et al., Russ. J. Inorg. Chem. 59, 355 (2014). https://doi.org/10.1134/S0036023614040111
D. G. Muratov, L. V. Kozhitov, and A. V. Popkova, Russ. J. Inorg. Chem. 61, 1312 (2016). https://doi.org/10.1134/S0036023616100168
I. A. Tkachenko, A. E. Panasenko, M. M. Odinokov, et al., Russ. J. Inorg. Chem. 65, 1142. https://doi.org/10.1134/S0036023620080173
M. M. Abdullaev, S. Y. Istomin, A. V. Sobolev, et al., Russ. J. Inorg. Chem. 64, 696 (2019). https://doi.org/10.1134/S0036023619060032
A. S. Kamzin, P. Lampen-Kelley, and M. H. Phan, Phys. Solid State 58, 792 (2016). https://doi.org/10.1134/S1063783416040089
V. G. Kostishin, R. M. Vergazov, V. G. Andreev, et al., Izv. VUZov. Mater. Elektron. Tekh. 18 (2010).
V. G. Kostishin, R. M. Vergazov, V. G. Andreev, et al., Izv. VUZov. Mater. Elektron. Tekh. 33 (2011).
V. G. Kostishin, R. M. Vergazov, S. B. Men’shova, and I. M. Isaev, Ros. Tekhnol. J. 8, 878 (2020). https://doi.org/10.32362/2500-316X-2020-8-6-87-108
V. G. Kostishin, R. M. Vergazov, S. B. Men’shova, et al., Zavod. Lab. 87, 30 (2021). https://doi.org/10.26896/1028-6861-2021-87-1-30-34
F. Menil, J. Phys. Chem. Solids 46, 763 (1985). https://doi.org/10.1016/0022-3697(85)90001-0
V. V. Korovushkin, A. V. Trukhanov, V. G. Kostishin, et al., Inorg. Mater. 56, 707 (2020). https://doi.org/10.1134/S0020168520070080
WWW-MINCRIST. Crystallographic and Crystal-Chemical Database for Minerals and Their Analogues (Institute of Experimental Mineralogy, Russian Academy of Sciences, 2021). http: //database.iem.ac.ru/mincryst/rus/index.php (Application Date April 28, 2021).
B. P. Nikol’skii and O. N. Grigorov, Chemist’s Handbook, vol. 1 (Khimiya, Leningrad, 1966) [in Russian].
A. V. Knyazev, N. N. Smirnova, M. Maczka, et al., Thermochim. Acta 559, 40 (2013). https://doi.org/10.1016/j.tca.2013.02.01
A. V. Knyazev, N. G. Chernorukov, S. S. Knyazeva, et al., Vest. Nizh. Gos. Univ. Ser. Khim. 4, 58 (2014).
E. W. Gorter, Phillips Res. Rep. 9, 295 (1954).
K. Haneda and A. H. Morrish, Phys. Lett. A 64, 259 (1977). https://doi.org/10.1016/0375-9601(77)90736-8
Sh. Sh. Bashkirov, A. B. Liberman, and V. I. Sinyavskii, Ferrite Magnetic Microstructure (Izd-vo Kazanskogo Universiteta, Kazan, 1978) [in Russian].
I. N. Zakharova, M. A. Shipilin, V. P. Alekseev, et al., Tech. Phys. Lett. 38, 55 (2012). https://doi.org/10.1134/S1063785012010294
K. Volenic, M. Seberini, and J. Neid, Chech. J. Phys. 25, 1063 (1975). https://doi.org/10.1007/BF01597585
J. B. Goodenough, Magnetism and the Chemical Bond (Interscience Publishers, New York, 1963).
Funding
This study was supported by the Russian Science Foundation (agreement no. 19-19-00694, May 6, 2019).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare no conflicts of interest.
Additional information
Translated by G. Kirakosyan
Rights and permissions
About this article
Cite this article
Isaev, I.M., Kostishin, V.G., Korovushkin, V.V. et al. Crystal Chemistry and Magnetic Properties of Polycrystalline Spinel Ferrites Li0.33Fe2.29Zn0.21Mn0.17O4. Russ. J. Inorg. Chem. 66, 1917–1924 (2021). https://doi.org/10.1134/S0036023621120056
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023621120056