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Transformations of Polymers of 4,4'-Dipyridyl and Cobalt(II) and Manganese(II) Cymantrenates in the Presence of N-Donors of Different Denticity

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Abstract

It has been found that the reactions of a suspension of 1D-coordination polymers (CPs) {(µ-dipy)2Mn2[µ-(OOCC5H4)Mn(CO)3]2[η2-(OOCC5H4)Mn(CO)3]2·2MeOH}n and {[µ-dipy)Co[(OOCC5H4)Mn(CO)3]2[O(H)Me]2}n (where dipy is 4,4'-dipy) with monodentate pyrazole (Hpz) and 3,5-dimethylpyrazole (Hdmpz) upon boiling in CH2Cl2 lead to the formation of 1D-CPs {µ-dipy)Mn[(OOCC5H4)Mn(CO)3]2(Hpz)2}n (1) and {(µ-dipy)Co[η2-(OOCC5H4)Mn(CO)3][(OOCC5H4)Mn(CO)3](Hdmpz)· Hdmpz}n (2), respectively. In the initial manganese(II) polymer, a binuclear fragment with coordination of two Hpz molecules by a metal atom in 1 is destroyed, and in the case of cobalt(II), two alcohol molecules are replaced by an Hdmpz molecule, and one of the anions becomes η2-coordinated. As a result of the reaction of the initial cobalt(II) CP with 1,10-phenanthroline (Phen) containing a water molecule, binuclear complex Co2[(OOCC5H4)Mn(CO)3]4(Phen)2(µ-dipy)(OH2)2 (3) is formed. The synthesized compounds 1–3 were studied by chemical analysis, IR spectroscopy, and X-ray diffraction analysis.

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ACKNOWLEDGMENTS

X-ray diffraction studies of complexes and IR spectral studies were carried out using the equipment of the Center for Collective Use of the Physical Methods of Investigation at the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, which functions with the support of the State Assignment of the Kurnakov Institute RAS in the field of fundamental scientific research.

Funding

This work was carried out within the framework of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental scientific research.

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, 119991, Moscow, Russia

    M. A. Uvarova & S. E. Nefedov

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  1. M. A. Uvarova
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  2. S. E. Nefedov
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Correspondence to S. E. Nefedov.

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Translated by V. Avdeeva

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Uvarova, M.A., Nefedov, S.E. Transformations of Polymers of 4,4'-Dipyridyl and Cobalt(II) and Manganese(II) Cymantrenates in the Presence of N-Donors of Different Denticity. Russ. J. Inorg. Chem. 66, 1660–1668 (2021). https://doi.org/10.1134/S0036023621110218

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