Abstract
The SnSe–Sb2Se3–Se system was studied by the emf method and X-ray powder diffraction analysis, and the diagram of solid-phase equilibria at 400 K was constructed. The partial thermodynamic functions of SnSe in various phase regions of the studied system were calculated from the measured emf of concentration cells with respect to a SnSe electrode in the temperature range 300–450 K. These data together with the corresponding thermodynamic functions of SnSe and Sb2Se3 were used to calculate the partial molar functions of tin in alloys, and also the standard thermodynamic functions of formation and standard entropies of the compounds SnSe2, Sn2Sb6Se11, SnSb2Se4, and Sn2Sb2Se5.
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REFERENCES
N. Alonso-Vante, Chalcogenide Materials for Energy Conversion: Pathways to Oxygen and Hydrogen Reactions (Springer Int. Publ. AG, Cham, Switzerland, 2018). https://doi.org/10.1007/978-3-319-89612-0
Applications of Chalcogenides: S, Se, and Te, Ed. by G. K. Ahluwalia (Springer Int. Publ. AG, Cham, Switzerland, 2017). https://doi.org/10.1007/978-3-319-41190-3
Chalcogenide: From 3D to 2D and Beyond, Ed. by X. Liu, S. Lee, J. K. Furdyna, T. Luo, and Y-H. Zhang (Elsevier, Duxford, UK, 2020). https://doi.org/10.1016/C2017-0-03585-1
Chalcogenides: Advances in Research and Applications, Ed. by W. Phillips (Nova Sci. Publ., Inc., Hauppauge, NY, USA, 2018).
E. Greenberg, B. Hen, S. Layek, et al., J. Phys. Rev. B 95, 064 514 (2017). https://doi.org/10.1103/PhysRevB.95.064514
R. Matsumoto, Z. Hou, H. Hara, et al., Appl. Phys. Express 11, 093 101 (2018). https://doi.org/10.7567/APEX.11.093101
A. Kosuga, K. Nakai, M. Matsuzawa, et al., J. Alloys Compd. 618, 463 (2015). https://doi.org/10.1016/j.jallcom.2014.08.183
V. S. Zemskov, L. E. Shelimova, P. P. Konstantinov, et al., Inorg. Mater. Appl. Res. 4, 77 (2013). https://doi.org/10.1134/S2075113313020196
F. von Rohr, A. Schilling, and R. J. Cava, J. Phys.: Condens. Matter 25, 075 804 (2013). https://doi.org/10.1088/0953-8984/25/7/075804
T. V. Quang and M. Kim, J. Korean Phys. Soc. 74, 256 (2019). https://doi.org/10.3938/jkps.74.256
B. A. Kuropatwa and H. Kleinke, Z. Anorg. Allg. Chem. 638, 2640 (2012). https://doi.org/10.1002/zaac.201200284
M. B. Babanly, E. V. Chulkov, Z. S. Aliev, et al., Russ. J. Inorg. Chem. 62, 1703 (2017). https://doi.org/10.1134/S0036023617130034
I. A. Shvets, I. I. Klimovskikh, Z. S. Aliev, et al., J. Phys. Rev. B 100, 195 127 (2019). https://doi.org/10.1103/PhysRevB.100.195127
M. G. Vergniory, T. V. Menshchikova, I. V. Silkin, et al., J. Phys. Rev. B 92, 045 134 (2015). https://doi.org/10.1103/physrevb.92.045134
D. Pacile, S. V. Eremeev, M. Caputo, et al., Phys. Status Solidi RRL, 1 800 341 (2018). https://doi.org/10.1002/pssr.201800341
M. Papagno, S. Eremeev, J. Fujii, et al., ACS Nano 10, 3518 (2016). https://doi.org/10.1021/acsnano.5b07750
Y. Hattori, Y. Tokumoto, K. Kimoto, et al., Sci. Rep. 10, 7957 (2020). https://doi.org/10.1038/s41598-020-64742-6
I. A. Shvets, I. I. Klimovskikh, Z. S. Aliev, et al., J. Phys. Rev. B 96, 235 124 (2017). https://doi.org/10.1103/physrevb.96.235124
P. Mal, G. Bera, G. R. Turpu, et al., J. Phys. Chem. Chem. Phys. 21, 15 030 (2019). https://doi.org/10.1039/c9cp01494b
T. Matsushita and K. Mukai, Chemical Thermodynamics in Materials Science: From Basics to Practical Applications (Springer Nature Singapore Pte Ltd., Singapore, 2018). https://doi.org/10.1007/978-981-13-0405-7
G. F. Voronin and Ya. I. Gerasimov, Thermodynamics and Semiconductor Materials Science (MIET, Moscow, 1980), pp. 3–10 [in Russian].
M. B. Babanly, L. F. Mashadiyeva, D. M. Babanly, et al., Russ. J. Inorg. Chem. 64, 1649 (2019). https://doi.org/10.1134/S0036023619130035
S. Z. Imamaliyeva, D. M. Babanly, D. B. Tagiev, et al., Russ. J. Inorg. Chem. 63, 1703 (2018). https://doi.org/10.1134/S0036023618130041
M. M. Asadov, S. N. Mustafaeva, D. B. Tagiyev, et al., Russ. J. Inorg. Chem. 65, 733 (2020). https://doi.org/10.1134/S0036023620050022
E. N. Ismailova, L. F. Mashadieva, I. B. Bakhtiyarly, et al., Russ. J. Inorg. Chem. 64, 801 (2019). https://doi.org/10.1134/S0036023619060093
I. B. Bakhtiyarly, R. D. Kurbanova, A. S. Abdullaeva, et al., Russ. J. Inorg. Chem. 64, 890 (2019). https://doi.org/10.1134/S0036023619070039
A. V. Kertman, Russ. J. Inorg. Chem. 64, 130 (2019). https://doi.org/10.1134/S0036023619010133
F. N. Guseinov, K. N. Babanly, I. I. Aliev, et al., Russ. J. Inorg. Chem. 57, 100 (2012). https://doi.org/10.1134/S003602361201010X
F. N. Guseinov, A. E. Seidzade, Yu. A. Yusibov, et al., Inorg. Mater. 53, 354 (2017). https://doi.org/10.1134/S0020168517040057
M. B. Babanly, F. N. Guseinov, G. B. Dashdyeva, et al., Inorg. Mater. 47, 235 (2011). https://doi.org/10.1134/S0020168511030022
M. B. Babanly, A. V. Shevelkov, F. N. Guseinov, et al., Inorg. Mater. 47, 712 (2011). https://doi.org/10.1134/S002016851107003X
Sh. H. Mansimova, R. J. Mirzoeva, L. F. Mashadiyeva, et al., J. Appl. Sol. Stat. Chem., No. 4, 104 (2018). https://doi.org/10.18572/2619-0141-2018-4-5-104-111
T. A. Ostapyuk, I. M. Yermiychuk, O. F. Zmiy, et al., Chem. Met. Alloys 2, 164 (2009). https://doi.org/10.30970/cma2.0100
W. Wobst, J. Less Common Metals 14, 77 (1968).
G. G. Gospodinov, I. I. Odin, and A. V. Novoselova, Inorg. Mater. 11, 1211 (1975).
J. Chang and S. Chen, Metall. Mater. Trans. E 4, 89 (2017). https://doi.org/10.1007/s40553-017-0110-8
J. Shen and R. Blachnik, J. Therm. Acta 399, 245 (2003). https://doi.org/10.1016/s0040-6031(02)00461-6
E. N. Ismailova, I. B. Bakhtiyarly, and M. B. Babanly, J. Chem. Probl., No. 2, 250 (2020). https://doi.org/10.32737/2221-8688-2020-2-250-256
P. K. Smith and J. B. Parise, Acta Crystallogr., Sect. B 41, 84 (1985). https://doi.org/10.1107/S0108768185001665
A. Mukherjee, Jpn. J. Appl. Physics 20, 681 (1982).
J. Emsley, The Elements, 3rd ed. (Clarendon, Oxford, 1998).
T. B. Massalski, Binary Alloy Phase Diagrams, 2nd ed. (ASM Int., Mat. Park. Ohio, 1990).
M. B. Babanly and Yu. A. Yusibov, in Electrochemical Methods in Thermodynamics of Inorganic Systems (ELM, Baku, 2011) [in Russian].
A. G. Morachevskii, G. F. Voronin, V. A. Geiderikh, and I. B. Kutsenok, Electrochemical Investigation Methods in Thermodynamics of Metal Systems (ITsK Akademkniga, Moscow, 2003) [in Russia].
V. P. Vassiliev and V. A. Lysenko, Electrochim. Acta 222, 1770 (2016). https://doi.org/10.1016/j.electacta.2016.11.075
V. R. Sidorko, L. V. Goncharuk, and R. V. Antonenko, Powder Metal. Metal Ceramics 47, 234 (2008). https://doi.org/10.1007/s11106-008-9009-3
S. Z. Imamaliyeva, S. S. Musayeva, D. M. Babanly, et al., Thermochim. Acta 679, 178 319 (2019). https://doi.org/10.1016/j.tca.2019.178319
E. N. Ismayilova, D. M. Babanly, V. P. Zlomanov, et al., J. New Mater. Comp. Appl., No. 3 (2020).
Thermal Constants of Substances: Database (Institute of Thermal Physics of Extreme States, Joint Institute of High-Temperatures, Moscow, Russia; Chemical Faculty, Moscow State University, Moscow, Russia) [in Russian]. http://www.chem.msu.su/cgi-bin/tkv.pl?show= welcom.html.
Materials Thermochemistry, 6th ed., Ed. by C. B. Alcock, O. Kubaschewski, and P. J. Spencer (Butterworth-Heinemann, Oxford, 1993).
I. Barin, Thermochemical Data of Pure Substances, 3rd ed. (VCH, New York, 2008).
Ya. I. Gerasimov, A. N. Krestovnikov, and S. I. Gorbov, Chemical Thermodynamics in Non-Ferrous Metal Industry: Handbook (Metallurgiya, Moscow, 1974) Vol. 6, p. 312.
B. W. Howlett, S. Misra, and M. Bever, Trans. Metall. Soc. AIME 230, 1367 (1964).
B. T. Melekh, N. B. Stepanova, and T. A. Fomina, Zh. Fiz. Khim. 45, 2018 (1971).
ACKNOWLEDGMENTS
This work was performed at the International Joint Research Laboratory “Advanced Materials for Spintronics and Quantum Computing” established between the Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan, and the Donostia International Physics Center, Donostia–San Sebastián, Gipuzkoa, Basque Country, Spain.
Funding
This work was supported in part by the Science Development Foundation of the President of Azerbaijan Republic (grant no. EİF-BGM-4-RFTF-1/2017-21/11/4-М-12).
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Translated by V. Glyanchenko
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Ismailova, E.N., Mashadieva, L.F., Babanly, D.M. et al. Diagram of Solid-Phase Equilibria in the SnSe–Sb2Se3–Se System and Thermodynamic Properties of Tin Antimony Selenides. Russ. J. Inorg. Chem. 66, 96–103 (2021). https://doi.org/10.1134/S0036023621010046
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DOI: https://doi.org/10.1134/S0036023621010046