Skip to main content
SpringerLink
Log in

Effect of Polysaccharide Additions on the Anion-Exchange Deposition of Cobalt Ferrite Nanoparticles

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

A facile and rapid method easily reproducible in ordinary laboratory settings is proposed for preparing nanosized cobalt ferrite powders, where the precipitate used is a strongly basic anion exchange resin in the OH form. The effects caused by additions of polysaccharides having various chain natures and various molar weights on the composition, yield, and particle size of the deposition product are studied. Suggested mechanisms underlying these effects are studied. This method makes it possible to appreciably reduce the precursor annealing temperature compared to that in the state-of-art methods for preparing similar oxide systems due to the formation of highly reactive precursors. Optimal conditions are found to prepare stoichiometric precursors such that, once annealed at 600°C, would form a CoFe2O4 pure phase with particle sizes of 10–20 nm. The stability of hydrosols of the thus-prepared cobalt ferrite nanoparticles is studied by dynamic and electrophoretic light scattering. The prepared material is found to be useful for the design of magnetic core–shell hybrid nanostructures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. U. Sitize and H. Sato, Ferrites (Mir, Moscow, 1964 (translated from Japanese) [in Russian].

  2. I. C. Covaliu, J. Neamtua, G. Georgescua, et al., J. Nanomaterials Biostructures 6, 245 (2011).

    Google Scholar 

  3. A. A. Il’in, A. P. Il’in, N. N. Smirnov, et al., Khim. Khim. Tekhnol. 53, 86 (2010).

    Google Scholar 

  4. V. M. Talanov, Pat. 2010135592/05, Byull. Izobret., No. 23 (2013).

  5. N. Rezlescu, E. Rezlescu, F. Tudorache, et al., Roman. Repts Phys. 61, 223 (2009).

    CAS  Google Scholar 

  6. M. Kanagaraj, P. Sathishkumar, G. K. Selvan, et al., Indian J. Pure Appl. Phys. 52, 124 (2014).

    CAS  Google Scholar 

  7. T. George, S. Joseph, A. T. Sunny, et al., J. Metastable Nanocryst. Mater., No. 23, 41 (2005).

  8. I. V. Kasy Viswanath, Y. L. N. Murthy, et al., Int. J. Chem. Sci. 11, 64 (2013).

    Google Scholar 

  9. I. V. Lisnevskaya, I. A. Bobrova, A. V. Petrova, et al., Russ. J. Inorg. Chem. 57, 474 (2012).

    Article  CAS  Google Scholar 

  10. I. V. Lisnevskaya, I. A. Bobrova, and T. G. Lupeiko, J. Magn. Magn. Mater. 51, 507 (2017).

    CAS  Google Scholar 

  11. N. Rezlescu, E. Rezlescu, F. Tudorache, et al., Roman. Repts in Phys. 61, 223 (2009).

    CAS  Google Scholar 

  12. S. S. Kader, D. P. Paul, S. M. Hoque, et al., Int. J. Mater., Mechan. Manuf. 2, 5 (2014).

    CAS  Google Scholar 

  13. S. V. Saikova, M. V. Panteleeva, and R. B. Nikolaeva, Russ. J. Appl. Chem. 75, 1787 (2002).

    Article  CAS  Google Scholar 

  14. G. L. Pashkov, C. V. Saikova, M. V. Panteleeva, et al., Zh. Siber. Fed. Univ., Ser. Khim. 2, 150 (2009).

    Google Scholar 

  15. G. L. Pashkov, S. V. Saikova, M. V. Panteleeva, et al., Theor. Found. Chem. Eng. 48, 671 (2014).

    Article  CAS  Google Scholar 

  16. G. L. Pashkov, S. V. Saikova, M. V. Panteleeva, et al., Steklo Keram. 71, 19 (2014).

    Google Scholar 

  17. A. I. Vulikh, Ion Exchange (Khimiya, Moscow, 1973) [in Russian].

    Google Scholar 

  18. S. V. Saikova, E. A. Kirshneva, M. V. Panteleeva, et al., Russ. J. Inorg. Chem. 64, 1191 (2019). https://doi.org/10.1134/S0036023619100127

    Article  CAS  Google Scholar 

  19. S. A. Shapiro, Analytical Chemistry (Vysshaya Shkola, Moscow, 1973) [in Russian].

  20. Powder Diffraction File (JCPDS), Nos. 43-1458; 13-398.

  21. Powder Diffraction File (JCPDS), No. 24-0072.

  22. Powder Diffraction File (JCPDS), No. 01-1152.

  23. S. V. Saikova, G. L. Pashkov, and M. V. Panteleeva, A Monograph (Sib. Feder. Univ., Krasnoyarsk, 2018) [in Russian].

    Google Scholar 

  24. T. V. Trofimova, A. Yu. Pavlikov, and S. V. Saikova, Vestn. Permsk. Univ., Ser. Khim. 7, 137 (2017).

    Google Scholar 

  25. T. Itano, J. Japan Soc. Air Poll. 18, 595 (1983). https://doi.org/10.11298/taiki1978.18.595

    Article  Google Scholar 

  26. L. M. Amreeva, G. Z. Zainelova, and B. Z. Medeubaeva, Meditsina 159 (9), 42 (2015).

    Google Scholar 

  27. G. L. Pashkov, S. V. Saikova, and M. V. Panteleeva, Theor. Found. Chem. Eng. 50 (4), 575 (2016). https://doi.org/10.1134/S0040579516040254

    Article  CAS  Google Scholar 

  28. G. S. Nikolic and M. D. Cakic, Colloid J. 69, 464 (2007). https://doi.org/10.1134/S1061933X07040084

    Article  CAS  Google Scholar 

  29. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley, New York, 1986; Mir, Moscow, 1991).

  30. T. Kawaguchi and M. Hasegawa, J. Mater. Sci.: Mater. Med. 11, 31 (2017). https://doi.org/10.1023/A:1008933601813

    Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

Instruments of the Shared Facilities Centers of the Cola Scientific Center of the Russian Academy of Sciences, and the Siberian Federal University were used in this study.

Funding

This study was financially supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, and the Krasnoyarsk Regional Science Fund in the frame of project no. 18-43-243014 entitled “Synthesis of Magnetic Core–Gold Shell Nanoparticles for Biomedical and Catalytic Applications.”

Author information

Authors and Affiliations

  1. Federal Siberian University, 660041, Krasnoyarsk, Russia

    S. V. Saikova, T. V. Trofimova, A. Yu. Pavlikov & A. S. Samoilo

Authors
  1. S. V. Saikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. V. Trofimova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Yu. Pavlikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Samoilo
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. V. Saikova.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by O. Fedorova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Saikova, S.V., Trofimova, T.V., Pavlikov, A.Y. et al. Effect of Polysaccharide Additions on the Anion-Exchange Deposition of Cobalt Ferrite Nanoparticles. Russ. J. Inorg. Chem. 65, 291–298 (2020). https://doi.org/10.1134/S0036023620030110

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023620030110

Keywords:

Search

Navigation