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A Photoluminescent Cd(II) Coordination Polymer with Highly Selective Detection for Nitrophenol

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Abstract

A cadmium(II) coordination polymer (CP), namely [Cd(H2L2–)(2,2′-bipy)]n (1) based on 3‑(3′,5′-dicarboxyphenyl)pyridine-2,6-dicarboxylic acid, has been synthesized under hydrothermal conditions. Compound 1 crystallizes in the orthorhombic system Pbca space group and features a 1D infinite Zigzag chain structure, further extending into a 3D supramolecular network through O–H\( \cdots \)O hydrogen bond interactions. CP 1 exhibits highly selective and sensitive luminescent detection for nitrophenol in ethanol solution with quenching efficiency up to 2.84 × 104 M–1 and a low detection limit of 4.4 μM. Remarkably, CP 1 might be a potential luminescent sensor material for nitrophenol.

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ACKNOWLEDGMENTS

This work was supported by grants from the Natural Science Foundation of China (no. 21761030), the research projects of colleges and universities in Gansu provinc (no. 2017A-075), and Tianshui Normal University ‘QinglanTalents’ Project.

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  1. College of Chemical Engineering and Technology, Tianshui Normal University, 741000, Tianshui, China

    Peng Wang, Shi-Jia Long & Chang-Dai Si

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  1. Peng Wang
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Correspondence to Shi-Jia Long or Chang-Dai Si.

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Peng Wang, Long, SJ. & Si, CD. A Photoluminescent Cd(II) Coordination Polymer with Highly Selective Detection for Nitrophenol. Russ. J. Inorg. Chem. 64, 1769–1774 (2019). https://doi.org/10.1134/S003602361914016X

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