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Structural Features of Monomeric Octahedral Monooxo d2-Rhenium(V) Complexes [ReO(Lmono)(\(L_{{{\text{tetra}}}}^{n}\))] with Oxygen Atoms of Tridentate Chelate Ligands OХ3, Х = O, N, or P (\(L_{{{\text{tetra}}}}^{n}\))

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Abstract

The structural features of six mononuclear octahedral monooxo d2-Re(V) complexes [ReO(Lmono)\(\left( {{\text{L}}_{{{\text{tetra}}}}^{n}} \right)\)] with tetradentate chelate (O, Х3; Х = O, N, P) \(\left( {{\text{L}}_{{{\text{tetra}}}}^{n}} \right)\) and monodentate (Lmono) ligands are discussed. The O\(\left( {{\text{L}}_{{{\text{tetra}}}}^{n}} \right)\) atoms are always located in the trans positions to the multiply bound O(oxo) ligands.

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ACKNOWLEDGMENTS

The author is grateful to A.V. Churakov for his help in searching for data from Cambridge Structural Database.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. S. Sergienko

  2. All-Russia Institute for Scientific and Technical Information, Russian Academy of Sciences, 125190, Moscow, Russia

    V. S. Sergienko

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  1. V. S. Sergienko
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Correspondence to V. S. Sergienko.

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Translated by V. Avdeeva

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Sergienko, V.S. Structural Features of Monomeric Octahedral Monooxo d2-Rhenium(V) Complexes [ReO(Lmono)(\(L_{{{\text{tetra}}}}^{n}\))] with Oxygen Atoms of Tridentate Chelate Ligands OХ3, Х = O, N, or P (\(L_{{{\text{tetra}}}}^{n}\)). Russ. J. Inorg. Chem. 64, 1127–1131 (2019). https://doi.org/10.1134/S0036023619090183

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