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Synthesis and Investigation of Thermodynamic Properties of Cu5V2O10

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Cu5V2O10 is prepared by solid-phase synthesis via sequential air calcination of a stoichiometric CuO-V2O5 mixture. Its high-temperature heat capacity is measured by differential scanning calorimetry. The thermodynamic properties (enthalpy and entropy changes and scaled Gibbs free energy) are calculated using the experimental dependence Cp =f(T). It is shown that specific heat capacity correlates with the composition of oxides in the CuO−V2O5 system.

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References

  1. A. A. Fotiev, B. V. Slobodin, and M. Ya. Khodos, Vanadates: Composition, Synthesis, Structure, and Properties (Nauka, Moscow, 1988) [in Russian].

    Google Scholar 

  2. P. Perrot, Refractory Metal Systems: Phase Diagrams, Crystallographic and Thermodynamic Data (Springer, Berlin/Heidelberg, 2010).

    Google Scholar 

  3. B. V. Slobodin, L. L. Surat, and R. F. Samigullina, Russ. J. Inorg. Chem. 54, 797 (2009). https://doi.org/10.1134/S0036023609050192

    Article  Google Scholar 

  4. Z. He, C. Lin, W. Chen, et al., J. Am. Chem. Soc. 133, 1298 (2011). https://doi.org/10.1021/ja110394j

    Article  CAS  PubMed  Google Scholar 

  5. T. Hillel and Y. Ein-Eli, J. Power Sources 229, 112 (2013). https://doi.org/10.1016/j.jpowsour.2012.11.128

    Article  CAS  Google Scholar 

  6. W. Guo, W. D. Chemelewski, O. Mabayoje, et al., J. Phys. Chem. C 119, 27220 (2015). https://doi.org/10.1021/acs.jpcc.5b07219

    Article  CAS  Google Scholar 

  7. T. Kawada, S. Hinokuma, and M. Machida, Catal. Today 242, 268 (2015). https://doi.org/10.1016/j.cattod.2014.05.023

    Article  CAS  Google Scholar 

  8. J. M. Hughes and C. G. Hadidiacos, Am. Mineral. 70, 193 (1985).

    CAS  Google Scholar 

  9. G. Dabrowska and E. Filipek, J. Thermal. Anal. Calorim. 93, 839 (2008). https://doi.org/10.1007/s10973-008-9301-y

    Article  CAS  Google Scholar 

  10. A. V. Prokofiev and R. K. Kremer, J. Cryst. Growth 231, 498 (2001). https://doi.org/10.1007/s12043-010-0103-y

    Article  CAS  Google Scholar 

  11. S. N. Bhatia, M. Mohapatra, R. Nirmala, et al., Pramana. J. Phys. 74, 833 (2010). https://doi.org/10.1007/s12043-010-0103-y

    Article  CAS  Google Scholar 

  12. L. T. Denisova, N. V. Belousova, V. M. Denisov, and N. A. Galiakhmetova, Phys. Solid State 59, 1270 (2017). https://doi.org/10.1134/S1063783417060075

    Article  CAS  Google Scholar 

  13. L. A. Solovyov, J. Appl. Crystallogr. 37, 743 (2004). https://doi.org/10.1107/S0021889804015638

    Article  CAS  Google Scholar 

  14. R. D. Shannon and C. Calvo, Acta Crystallogr., Sect. B 29, 1338 (1973).

    Article  CAS  Google Scholar 

  15. V. M. Denisov, L. T. Denisova, L. A. Irtyugo, and V. S. Biront, Phys. Solid State 52, 1362 (2010). https://doi.org/10.1134/S1063783410070073

    Article  CAS  Google Scholar 

  16. L. T. Denisova, L. A. Irtyugo, Y. F. Kargin, et al., Inorg. Mater. 53, 93 (2017). https://doi.org/10.1134/S0020168517010046

    Article  CAS  Google Scholar 

  17. V. I. Pet’kov, A. V. Markin, and N. N. Smirnova, Russ. J. Phys. Chem. A 87, 1266 (2013). https://doi.org/10.1134/S0036024413070261

    Article  CAS  Google Scholar 

  18. A. M. Skuratov, V. P. Kolesov, and A. F. Vorob’ev, Thermochemistry (Mosk. Gos. Univ., Moscow 1966), Pt. II [in Russian].

    Google Scholar 

  19. A. F. Prekul, V. A. Kazantsev, N. I. Shchegolikhina, et al., Phys. Solid State. 50, 2013 (2008). https://doi.org/10.1134/S1063783408110024

    Article  CAS  Google Scholar 

  20. A. Jezierski and J. Kaczkowski, Phase Trans. 88(10), 1 (2015). https://doi.org/10.1080/01411594.2015.1007056

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Non-ferrous Metals and Materials Science, Siberian Federal University, Krasnoyarsk, 660041, Russia

    L. T. Denisova, N. V. Belousova, N. A. Galiakhmetova & V. M. Denisov

  2. Baikov Institute of Metallurgy and Materials Science, Moscow, 119991, Russia

    Yu. F. Kargin

Authors
  1. L. T. Denisova
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  2. Yu. F. Kargin
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  3. N. V. Belousova
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  4. N. A. Galiakhmetova
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  5. V. M. Denisov
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Correspondence to L. T. Denisova.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Neorganicheskoi Khimii, 2019, Vol. 64, No. 6, pp. 603–606.

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Denisova, L.T., Kargin, Y.F., Belousova, N.V. et al. Synthesis and Investigation of Thermodynamic Properties of Cu5V2O10. Russ. J. Inorg. Chem. 64, 725–728 (2019). https://doi.org/10.1134/S0036023619060056

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  • DOI: https://doi.org/10.1134/S0036023619060056

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