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Synthesis and Luminescent Properties of Europium(III, II) Phosphates

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Nanosized europium phosphates Eu3PO7, Eu(PO3)3, and Eu(PO3)3: Eu2+ have been prepared by low-temperature extraction-pyrolytic method. Optimal temperature and time of precursor pyrolysis for preparing luminophor containing europium in different oxidation states have been determined. Phosphate luminophore based on Eu3+ exhibit intense red luminescence with λmax ∼ 600–650 nm. Luminescence spectra of Eu(PO3)3: Eu2+ are characterized by emission bands in the region 400–700 nm typical for both Eu3+ (the bands of 5D0–7Fj(j = 0, 1, 2) transitions), and Eu2+ (the band of 4f65d → 8S7/2 transition). Luminescence-exciting wavelengths provide different contribution to the radiation intensity of both Eu2+ and Eu3+.

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russi an Academy of Sciences, Vladivostok, 690022, Russia

    N. I. Steblevskaya, M. V. Belobeletskaya, A. Yu. Ustinov & M. A. Medkov

  2. Far Eastern Federal University, Vladivostok, 690091, Russia

    A. Yu. Ustinov

Authors
  1. N. I. Steblevskaya
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  2. M. V. Belobeletskaya
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  3. A. Yu. Ustinov
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  4. M. A. Medkov
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Correspondence to N. I. Steblevskaya.

Additional information

Russian Text © N.I. Steblevskaya, M.V. Belobeletskaya, A.Yu. Ustinov, M.A. Medkov, 2019, published in Zhurnal Neorganicheskoi Khimii, 2019, Vol. 64, No. 2, pp. 146–152.

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Steblevskaya, N.I., Belobeletskaya, M.V., Ustinov, A.Y. et al. Synthesis and Luminescent Properties of Europium(III, II) Phosphates. Russ. J. Inorg. Chem. 64, 179–184 (2019). https://doi.org/10.1134/S0036023619020219

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  • DOI: https://doi.org/10.1134/S0036023619020219

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