Skip to main content
SpringerLink
Log in

Effect of the Synthesis Method on the Functional Properties of Lithium-Rich Complex Oxides Li1.2Mn0.54Ni0.13Co0.13O2

  • Synthesis and Properties Of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Layered Li-rich transition metal oxides are considered among the most promising cathode materials for high energy density lithium-ion batteries. It was studied how the method and conditions of synthesis of Li-rich oxides Li1.2Mn0.54Ni0.13Co0.13O2 affect their electrochemical properties. Coprecipitation methods and modified Pechini process were used. It was shown that it is necessary to carefully choose the synthesis conditions when using the modified Pechini method because of their significant effect on the morphology of Li-rich oxides. Samples were obtained with high electrochemical characteristics: capacity discharge of 260–270 mAh/g (16 mA/g) and 60–70 mAh/g (988 mA/g) within the voltage range of 2.5–4.8 V.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. Andre, S.-J. Kim, P. Lamp, et al., J. Mater. Chem. A 3, 6709 (2015). doi 10.1039/c5ta00361j

    Article  CAS  Google Scholar 

  2. M. M. Thackeray, S. H. Kang, C. S. Johnson, et al., J. Mater. Chem. 17, 3112 (2007). doi 10.1039/B702425H

    Article  CAS  Google Scholar 

  3. A. Manthiram, J. C. Knight, S.-T. Myung, et al., Adv. Energy Mater. 6, 1501010 (2016). doi 10.1002/aenm.201501010

    Article  CAS  Google Scholar 

  4. J. Zheng, P. Xu, M. Gu, et al., Chem. Mater. 27, 1381 (2015). doi 10.1021/cm5045978

    Article  CAS  Google Scholar 

  5. T. Ohzuku, M. Nagayama, K. Tsuji, et al., J. Mater. Chem. 21, 10179 (2011). doi 10.1039/C0JM04325G

    Article  CAS  Google Scholar 

  6. A. K. Shukle, Q. M. Ramasse, C. Ophus, et al., Nature Comm. 6, 8711 (2015). doi 10.1038/ncomms9711

    Article  CAS  Google Scholar 

  7. M. M. Thackeray, S. H. Kang, C. S. Johnson, et al., Electrochem. Commun. 8, 1531 (2006). doi 10.1016/j.elecom.2006.06.030

    Article  CAS  Google Scholar 

  8. H. Koga, L. Crogunnec, P. Mannessiez, et al., J. Phys. Chem. C 116, 13497 (2012). doi 10.1021/jp301879x

    Article  CAS  Google Scholar 

  9. M. Sathiya, G. Rousse, K. Ramesha, et al., Nature Mater. 12, 827 (2013). doi 10.1038/nmat3699

    Article  CAS  Google Scholar 

  10. P. Roziera and J. M. Tarascon, J. Electrochem. Soc. 162, A2490 (2015). doi 10.1149/2.0111514jes

    Google Scholar 

  11. P. K. Nayak, E. M. Erikson, F. Shipper, et al., Adv. Energy Mater. 8, 1702397 (2018). doi 10.1002/aenm.201702397

    Article  CAS  Google Scholar 

  12. L. Croguennec and M. R. Polacin, J. Am. Chem. Soc. 137, 3140 (2015). doi 10.1021/ja507828x

    Article  CAS  PubMed  Google Scholar 

  13. E. McCalla, A. W. Rowe, J. Camardese, et al., Chem. Mater. 25, 2716 (2013). doi 10.1021/cm401461m

    Article  CAS  Google Scholar 

  14. R. Shunmugasundaram, R. S. Arumugam, and J. R. Dahn, Chem. Mater. 27, 757 (2015). doi 10.1021/cm504583y

    Article  CAS  Google Scholar 

  15. S. Hy, H. Liu, M. Zhang, et al., Energy Environ. Sci. 9, 1931 (2016). doi 10.1039/c5ee03573b

    Article  CAS  Google Scholar 

  16. E. McCalla, C. M. Lowartz, C. R. Brown, et al., Chem. Mater. 25, 912 (2013). doi 10.1021/cm304002b

    Article  CAS  Google Scholar 

  17. E.-S. Lee, A. Huq, and A. Manthiram, J. Power Sources 240, 193 (2013). https://doi.org/10.1016/j.jpowsour.2013.04.010

    Article  CAS  Google Scholar 

  18. Y. Sun, Y. Shiosaki, Y. Xia, and H. Noguchi, J. Power Sources 159, 1353 (2006). doi 10.1016/j.jpowsour. 2005.12.037

    Article  CAS  Google Scholar 

  19. Y. Koyama, Y. Makimura, I. Tanaka, et al., J. Electrochem. Soc. 151, A1499 (2004). doi 10.1149/1.1783908

    Google Scholar 

  20. E. V. Makhonina, A. E. Medvedeva, V. S. Dubasova, et al., Int. J. Hydrogen Energy 41, 9901 (2016). doi 10.1016/j.ijhydene.2016.02.091

    Article  CAS  Google Scholar 

  21. W. Liu, G. C. Farrington, F. Chaput, et al., J. Electrochem. Soc. 143, 879 (1996).

    Article  CAS  Google Scholar 

  22. A. Boulineau, L. Croguennec, C. Delmas, et al., Chem. Mater. 21, 4216 (2009). doi 10.1021/cm900998n

    Article  CAS  Google Scholar 

  23. Z. H. Lu, L. Y. Beaulieu, R. A. Donaberger, et al., J. Electrochem. Soc. 149, A778 (2002). doi 10.1149/1.1471541

    Google Scholar 

  24. A. Rougier, P. Gravereau, and C. Delmas, J. Electrochem. Soc. 143, 1168 (1996). doi 10.1149/1.1836614

    Article  CAS  Google Scholar 

  25. X. Yu, Y. Lyu, and L. Gu, Adv. Energy Mater. 4, 1300950 (2014). doi 10.1002/aenm.201300950

    Article  CAS  Google Scholar 

  26. M. N. Ates, S. Mukerjee, and K. M. Abraham, RCS Adv. 5, 27375 (2015). doi 10.1039/c4ra17235c

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    L. S. Pechen, E. V. Makhonina, V. S. Pervov & I. L. Eremenko

  2. Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. Petersburg, 194021, Russia

    A. M. Rumyantsev & Yu. M. Koshtyal

  3. Center for National Technology Initiative “New Production Technologies”, Peter the Great St. Petersburg Polytechnical University, St. Petersburg, 195251, Russia

    A. M. Rumyantsev & Yu. M. Koshtyal

Authors
  1. L. S. Pechen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Makhonina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. Rumyantsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. M. Koshtyal
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. S. Pervov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. L. Eremenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. S. Pechen.

Additional information

Original Russian Text © L.S. Pechen, E.V. Makhonina, A.M. Rumyantsev, Yu.M. Koshtyal, V.S. Pervov, I.L. Eremenko, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 12, pp. 1522–1529.

This article participated in the Research Paper Competition at the VIII Conference of Young Scientists on General and Inorganic Chemistry (Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia, 2018).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pechen, L.S., Makhonina, E.V., Rumyantsev, A.M. et al. Effect of the Synthesis Method on the Functional Properties of Lithium-Rich Complex Oxides Li1.2Mn0.54Ni0.13Co0.13O2. Russ. J. Inorg. Chem. 63, 1534–1540 (2018). https://doi.org/10.1134/S0036023618120173

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023618120173

Keywords

Search

Navigation