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Synthesis, Crystal, and Molecular Structure of Bis(thiosemicarbazide)zinc(II) 1,5-Naphthalenedisulfonate Monohydrate [Zn(Tsc)2](1,5-Nds) · H2O

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Abstract

Complex [Zn(Tsc)2](Nds) · H2O (I) (Tsc is thiosemicarbazide, NH2NHC(=S)NH2, and 1,5-Nds2–is the double-deprotonated anion of 1,5-naphthalenedisulfonic acid, C10H6(SO3) 2-2 ) has been synthesized and studied by IR spectroscopy, thermogravimetry, and X-ray diffraction analysis. The structural units of crystal I are complex cations [Zn(Tsc)2]2+, anions (Nds)2–, and crystallization water molecules. The Zn atom is coordinated along the vertices of the distorted tetrahedron by two sulfur atoms and two nitrogen atoms of two bidentate chelate (S,N) Tsc ligands. The structural units of crystal I are joined together by a branched network of the N–H···O hydrogen bonds involving independent donor hydrogen atoms of the NH2 and NH groups of Tsc molecules (nine of ten, except for the H(6A) atom), all six independent acceptor oxygen atoms of the SO3 groups of the Nds2– anions, and two acceptor hydrogen atoms and one donor oxygen atom of the water molecule.

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References

  1. J. Cai, C.-H. Chen, X.-L. Feng, et al., J. Chem. Soc., Dalton Trans., No. 16, 2370 (2001).

    Article  CAS  Google Scholar 

  2. J. Cai, C.-H. Chen, C.-Z. Liao, et al., J. Chem. Soc., Dalton Trans., No. 7, 1137 (2001).

    Article  Google Scholar 

  3. L.-H. Huo, S. Gao, S.-X. Xu, et al., Acta Crystallogr., Sect. E 61, m449 (2005).

    Article  CAS  Google Scholar 

  4. G. M. Sheldrick, SHELXS-86: Program for Solution of Crystal Structures (Univ. of Göttingen, Göttingen, 1986).

    Google Scholar 

  5. G. M. Sheldrick, Acta Crystallogr., Sect. A 64, 112 (2007).

    Article  CAS  PubMed  Google Scholar 

  6. F. H. Allen, Acta Crystallogr., Sect. B 58, 380 (2002).

    Article  CAS  PubMed  Google Scholar 

  7. G. V. Romanenko, Z. A. Savel’eva, and S. V. Larionov, Zh. Strukt. Khim. 40, 93 (1999).

    Google Scholar 

  8. S. B. Novaković, G. A. Bogdanović, B. Fraisse, et al., J. Phys. Chem. A 111, 13492 (2007).

    Article  CAS  PubMed  Google Scholar 

  9. Y.-X. Tong, C. Y. Su, Z.-F. Zhang, et al., Acta Crystallogr., Sect. C 56, 44 (2000).

    Article  Google Scholar 

  10. L. Cavalca, M. Nardelli, and G. Branchi, Acta Crystallogr. 13, 688 (1960).

    Article  CAS  Google Scholar 

  11. J. E. V. Babb, A. D. Burrows, R. W. Harrington, and M. F. Mahon, Polyhedron 22, 673 (2003).

    Article  CAS  Google Scholar 

  12. B. Singh, R. Singh, R. V. Chaudhary, and K. P. Thakur, Indian J. Chem. 11, 174 (1973).

    CAS  Google Scholar 

  13. J. Perles, N. Snejko, M. Iglesias, et al., J. Mater. Chem. 19, 6504 (2009).

    Article  CAS  Google Scholar 

  14. D. Sun, N. Zhang, Z.-H. We, et al., J. Mol. Struct. 981, 80 (2010).

    Article  CAS  Google Scholar 

  15. D. Sun, F.-J. Liu, H.-J. Hao, et al., Cryst. Eng. Commun. 13, 5661 (2011).

    Article  CAS  Google Scholar 

  16. S. Wang, R. Zhang, J. Wang, et al., Chem. Res. Chin. Univ. 30, 9 (2014).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Mechnikov Odessa National University, Odessa, 65082, Ukraine

    T. V. Koksharova & T. S. Skakun

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    V. S. Sergienko, I. N. Polyakova & M. D. Surazhskaya

  3. All-Russian Institute for Scientific and Technical Information, Moscow, 125315, Russia

    V. S. Sergienko

Authors
  1. T. V. Koksharova
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  2. V. S. Sergienko
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  3. I. N. Polyakova
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  4. T. S. Skakun
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  5. M. D. Surazhskaya
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Corresponding author

Correspondence to V. S. Sergienko.

Additional information

Original Russian Text © T.V. Koksharova, V.S. Sergienko, I.N. Polyakova, T.S. Skakun, M.D. Surazhskaya, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 7, pp. 845–851.

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Koksharova, T.V., Sergienko, V.S., Polyakova, I.N. et al. Synthesis, Crystal, and Molecular Structure of Bis(thiosemicarbazide)zinc(II) 1,5-Naphthalenedisulfonate Monohydrate [Zn(Tsc)2](1,5-Nds) · H2O. Russ. J. Inorg. Chem. 63, 887–893 (2018). https://doi.org/10.1134/S0036023618070100

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  • DOI: https://doi.org/10.1134/S0036023618070100

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