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Synthesis, Molecular, and Crystal Structure of a Complex of Pentacoordinated Zinc with Chloride Ions and Pyridine-2-Carbaldehyde Hemiacetal

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Abstract

The reaction between pyridine-2-carbaldehyde and zinc chloride in wet MeCN yielded a zinc chelate complex with hemiacetal formed in situ from the hydrated pyridine-2-carbaldehyde and the second molecule of pyridine-2-carbaldehyde. According to X-ray diffraction data, the pentacoordinated environment of the zinc ion is formed by two chlorine atoms and the N,N',O-tridentate ligand. In the crystal, molecules are combined into a 3D supramolecular framework due to the intermolecular hydrogen bonds O–H···Cl, C–H···Cl, and π–π stacking interactions between pyridine rings.

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Authors and Affiliations

  1. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, 664033, Russia

    L. A. Grishchenko, L. N. Parshina, M. Ya. Khil’ko, V. I. Smirnov & T. N. Borodina

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  1. L. A. Grishchenko
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  2. L. N. Parshina
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  3. M. Ya. Khil’ko
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  4. V. I. Smirnov
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  5. T. N. Borodina
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Corresponding author

Correspondence to L. N. Parshina.

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Original Russian Text © L.A. Grishchenko, L.N. Parshina, M.Ya. Khil’ko, V.I. Smirnov, T.N. Borodina, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 7, pp. 839–844.

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Grishchenko, L.A., Parshina, L.N., Khil’ko, M.Y. et al. Synthesis, Molecular, and Crystal Structure of a Complex of Pentacoordinated Zinc with Chloride Ions and Pyridine-2-Carbaldehyde Hemiacetal. Russ. J. Inorg. Chem. 63, 881–886 (2018). https://doi.org/10.1134/S0036023618070082

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  • DOI: https://doi.org/10.1134/S0036023618070082

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