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The Effect of Concentration Parameters on Complexation in the Iron(0)–Iron(II)–Glycine–Water System

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Abstract

The processes of formation of iron(II) complexes in aqueous glycine solutions in the pH range of 1.0–8.0 at 298 K and ionic strength of 1 mol/L (NaClO4) are studied using Clark and Nikolskii’s oxidation potential method. The type and number of coordinated ligands, the nuclearity, and the total composition of the resulting complexes are determined. The following complex species are formed in the investigated system: [Fe(OH)(H2O)5]+, [FeHL(H2O)5]2+, [Fe(HL)(OH)(H2O)4]+, [Fe(OH)2(H2O)4]0, [Fe2(HL)2(OH)2(H2O)8]2+, and [Fe(HL)2(H2O)4]2+. Their formation constants are calculated by the successive iterations method using Yusupov’s theoretical and experimental oxidation function. The model parameters of the resulting coordination compounds are determined.

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References

  1. Kh. D. Yakubke and Kh. Eshkait, Amino Acids. Peptides. Proteins (Mir, Moscow, 1985) [in Russian].

    Google Scholar 

  2. Z. N. Yusupov, G. B. Eshova, and S. S. Saidov, Dokl. Akad. Nauk RT 51 (8), 620 (2008).

    Google Scholar 

  3. Albert, A. and Sergeant, E.P., Ionization Constants of Acids and Bases (Wiley, London, 1962).

    Google Scholar 

  4. The Chemist’s Handbook, Ed. by B. P. Nikol’skii and O. N. Grigorov (Khimiya, Moscow, 1965) [in Russian].

  5. M. M. Rakhimova, Doctoral Dissertation in Chemistry (Dushanbe, 2013).

    Google Scholar 

  6. O. V. Salishcheva, S. E. Kiselev, and N. E. Moldagulova, Sovrem. Problemy Nauki Obraz., No. 5 (2011). ISSN 2070-7428.

  7. N. S. Osmanov, Proceedings of the All-Russia Scientific Conference (with foreign participants) “Advances in Synthesis and Complex Formation” (Ros. Peoples’ Friendshiip Univ., Moscow, 2012) [in Russian].

    Google Scholar 

  8. Redoxmetry, Ed. by B. P. Nikol’skii and V. V. Pal’chevskii (Khimiya, Leningrad, 1975) [in Russian].

  9. M. M. Rakhimova, N. S. Yusufov, T. M. Nurmatov, et al., Am. Chem. J. 3 (2), 23 (2013).

    CAS  Google Scholar 

  10. M. M. Rakhimova, T. M. Nurmatov, N. Z. Yusupov, et al., Russ. J. Inorg. Chem. 58, 719 (2013).

    Article  CAS  Google Scholar 

  11. M. M. Rakhimova, T. M. Nurmatov, N. Z. Yusupov, et al., Russ. J. Inorg. Chem. 58, 746 (2013).

    Google Scholar 

  12. Yu. B. Koryakin and I. I. Angelov, Pure Chemicals (Khimiya, Moscow, 1974) [in Russian].

    Google Scholar 

  13. I. M. Kolthoff, R. Belcher, V. A. Stenger, and G. Matsuyama, Volumetric Analysis (Interscience, New York, 1957), Vol.3.

  14. G. Charlot, Les methodes de la chimie analytique: Analyse quantitative minerale (Masson, Paris, 1961).

    Google Scholar 

  15. Quick Reference Book of Physical and Chemical Quantities, Ed. by K. P. Mishchenko and A. A. Ravel’ (Khimiya, Leningrad, 1974) [in Russian].

  16. L. V. Kvyatkovskaya, G. B. Eshova, D. A. Davlatshoeva, and M. M. Rakhimova, Vestn. TNU, Nos. 1–4, 86 (2014).

    Google Scholar 

  17. Z. N. Yusupov, RT Patent No. 295, Byull. Izobret., No. 21 (2001).

Download references

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Authors and Affiliations

  1. Tajik National University, Dushanbe, 734025, Tajikistan

    G. B. Eshova, J. A. Davlatshoeva, M. M. Rakhimova, L. V. Kvyatkovskaya & M. O. Guriev

Authors
  1. G. B. Eshova
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  2. J. A. Davlatshoeva
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  3. M. M. Rakhimova
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  4. L. V. Kvyatkovskaya
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  5. M. O. Guriev
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Corresponding author

Correspondence to M. M. Rakhimova.

Additional information

Original Russian Text © G.B. Eshova, J.A. Davlatshoeva, M.M. Rakhimova, L.V. Kvyatkovskaya, M.O. Guriev, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 4, pp. 525–530.

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Eshova, G.B., Davlatshoeva, J.A., Rakhimova, M.M. et al. The Effect of Concentration Parameters on Complexation in the Iron(0)–Iron(II)–Glycine–Water System. Russ. J. Inorg. Chem. 63, 561–566 (2018). https://doi.org/10.1134/S0036023618040083

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  • DOI: https://doi.org/10.1134/S0036023618040083

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