Skip to main content
SpringerLink
Log in

Hydrogenation and Dehydrogenation of the Clathrate Na x Si136

  • Physical Methods of Investigation
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Samples of the clathrate Na x Si136 were saturated with hydrogen to 100 atm at 25°C in a Sievertstype apparatus and at pressures of 6 and 28 kbar in lentil-type high-pressure apparatuses at 100 and 250°C. X-ray powder diffraction analysis and Raman spectroscopy of the samples quenched after the saturation with hydrogen showed that the phase composition of the clathrates did not change. Heating of the quenched samples to room temperature in a thermal desorption setup produced not hydrogen, but hydrogen-containing gases, as we assumed, silanes. Heating to 650°C leads to decomposition of these compounds to form hydrogen.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. S. Kasper, P. Hagenmuller, and M. Pouchard, Science 150, 1713 (1965).

    Article  CAS  Google Scholar 

  2. G. K. Ramachandran, P. F. McMillan, J. J. Dong, et al., J. Solid State Chem. 154, 626 (2000).

    Article  CAS  Google Scholar 

  3. S. Latturner, B. B. Iverson, J. Sepa, et al., Phys. Rev. B 63, 125403 (2001).

    Article  Google Scholar 

  4. G. K. Ramachandran, J. Dong, and J. Diefenbacher, J. Solid State Chem. 145, 716 (1999).

    Article  CAS  Google Scholar 

  5. J. L. Cohn, G. S. Nolas, V. Fessatidis, et al., Phys. Rev. Lett. 82, 779 (1999).

    Article  CAS  Google Scholar 

  6. G. Nolas, T. Weakley, J. Cohn, et al., Phys. Rev. B 61, 3845 (2000).

    Article  CAS  Google Scholar 

  7. S. Yamanaka, E. Enishi, H. Fukuoka, et al., Inorg. Chem. 39, 56 (2000).

    Article  CAS  Google Scholar 

  8. D. Neiner, N. L. Okamoto, and C. L. Condron, J. Am. Chem. Soc. 129, 13857 (2007).

    Article  CAS  Google Scholar 

  9. D. Neiner, N. L. Okamoto, and P. Yu, Inorg. Chem. 49, 815 (2010).

    Article  CAS  Google Scholar 

  10. A. Ammar, C. Cros, M. Pouchard, et al., Solid State Sci. 393, 4006 (2004).

    Google Scholar 

  11. A. Ammar, C. Cros, M. Pouchard, et al., J. Phys. IV Fr. 123, 29 (2005).

    Article  CAS  Google Scholar 

  12. V. E. Antonov, I. O. Bashkin, S. S. Khasanov, et al., J. Alloys Comp. 330–332, 365 (2002).

    Article  Google Scholar 

  13. V. B. Son, A. A. Volodin, R. V. Denis, et al., Izv. Akad. Nauk, Ser. Khim., No. 8, 1971 (2016).

    Google Scholar 

  14. V. B. Son, Yu. Ya. Shimkus, B. P. Tarasov, et al., Al’tern. Energ. Ekol., No. 21, 100 (2015).

    Google Scholar 

  15. V. E. Antonov, I. O. Bashkin, A. V. Bazhenov, et al., Carbon 100, 465 (2016).

    Article  CAS  Google Scholar 

  16. V. S. Efimchenko, V. K. Fedotov, M. A. Kuzovnikov, et al., J. Phys. Chem. A 118, 10268 (2014).

    Article  CAS  Google Scholar 

  17. E. Reny, P. Gravereau, C. Croset, et al., J. Mater. Chem. 8, 2839 (1998).

    Article  CAS  Google Scholar 

  18. V. S. Efimchenko, V. E. Antonov, O. I. Barkalov, et al., J. Phys. Chem. B 112, 7026 (2008).

    Article  CAS  Google Scholar 

  19. W. L. Mao, H.-K. Mao, A. F. Goncharov, et al., Science 297, 2247 (2002).

    Article  CAS  Google Scholar 

  20. E. Hohmann, Z. Anorg. Allg. Chem. 257, 113 (1948).

    Article  CAS  Google Scholar 

  21. R. R. B. Correia, S. L. Cunha, R. Vivie-Riedle, et al., Chem. Phys. Lett. 186, 531 (1991).

    Article  CAS  Google Scholar 

  22. W. S. Tang, J.-N. Chotard, P. Raybaud, et al., Phys. Chem. Chem. Phys. 14, 13319 (2012).

    Article  CAS  Google Scholar 

  23. I. K. Kikoin, Tables of Physical Quantities (Atomizdat, Moscow, 1976) [in Russian].

    Google Scholar 

  24. B. Arkles, Silanes, Reprint from Kirk-Othmer Encyclopedia of Chemical Technology, 4th ed., Vol. 22, pp. 38–69 (Gelest, Tullytown, Pa., 1997).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. S. Efimchenko, O. I. Barkalov, V. I. Kulakov, K. P. Meletov, I. A. Sholin & D. V. Matveev

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. B. Son

  3. Moscow State University, Moscow, 119991, Russia

    B. M. Bulychev & D. I. Kapustin

Authors
  1. V. S. Efimchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. I. Barkalov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. I. Kulakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. B. Son
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. K. P. Meletov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. B. M. Bulychev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. I. A. Sholin
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. D. I. Kapustin
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. D. V. Matveev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. S. Efimchenko.

Additional information

Original Russian Text © V.S. Efimchenko, O.I. Barkalov, V.I. Kulakov, V.B. Son, K.P. Meletov, B.M. Bulychev, I.A. Sholin, D.I. Kapustin, D.V. Matveev, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 3, pp. 341–345.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Efimchenko, V.S., Barkalov, O.I., Kulakov, V.I. et al. Hydrogenation and Dehydrogenation of the Clathrate Na x Si136. Russ. J. Inorg. Chem. 63, 364–368 (2018). https://doi.org/10.1134/S0036023618030051

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023618030051

Search

Navigation