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Synthesis and Crystal Structure of Dinitratotetra(hexamethylphosphoric Triamide)-Lanthanum(III)Tetra(Isothiocyanato)Diammine Chromate(III)

  • Coordination Compounds
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Abstract

A new coordination compound having the formula [La(HMPA)4(NO3)2][Cr(NH3)2(NCS)4] (I), where HMPA is ((CH3)2N)3PO, has been synthesized and studied by X-ray diffraction. Studied crystals of compound I are monoclinic, space group P21/n, a = 15.0360(3) Å, b = 15.1214(3) Å, c = 26.7529(7) Å, β = 100.6610(10)°, V = 5977.7(9) Å3, Z = 2, ρcalc = 1.442 g/cm3, and R1 = 0.0453 for 7344 reflections with Fo ≥ 4σ(Fo).

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Authors and Affiliations

  1. Kuzbass State Technical University, Kemerovo, 650000, Russia

    A. A. Bobrovnikova, T. G. Cherkasova & E. S. Tatarinova

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    E. V. Peresypkina & A. V. Virovets

  3. Novosibirsk State University, Novosibirsk, 630090, Russia

    E. V. Peresypkina & A. V. Virovets

Authors
  1. A. A. Bobrovnikova
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  2. E. V. Peresypkina
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  3. A. V. Virovets
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  4. T. G. Cherkasova
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  5. E. S. Tatarinova
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Corresponding author

Correspondence to T. G. Cherkasova.

Additional information

Original Russian Text © A.A. Bobrovnikova, E.V. Peresypkina, A.V. Virovets, T.G. Cherkasova, E.S. Tatarinova, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 1, pp. 39–45.

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Bobrovnikova, A.A., Peresypkina, E.V., Virovets, A.V. et al. Synthesis and Crystal Structure of Dinitratotetra(hexamethylphosphoric Triamide)-Lanthanum(III)Tetra(Isothiocyanato)Diammine Chromate(III). Russ. J. Inorg. Chem. 63, 34–39 (2018). https://doi.org/10.1134/S0036023618010047

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  • DOI: https://doi.org/10.1134/S0036023618010047

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