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5,15-bis(4′-methoxyphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphin axial complexes of rhenium: Synthesis and reactions in protic solvents

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Abstract

The spectral (UV–Vis, IR, and NMR 1H) properties and the state of oxorhenium(V) complexes with 5,15-bis(4′-methoxyphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphin H2P (O=Re(X)P) in protic solvents have been studied depending on the axial trans-ligand X– (X = Cl, OPh, or OH). The O=Re(Cl)P, O=Re(OPh)P, and O=Re(OH)P in AcOH and CF3COOH are subjected to reaction of substitution their axial ligands with solvent molecules or anions, while remaining stable to the dissociation of M–N bonds and to oxidation both to the macrocyclic ligand and to the central metal cation. Quantitative parameters of the coordination of molecular oxygen by O=Re(Cl)P in 17.4–18.2 M H2SO4 to form O=Re(O2)P+ · Cl– have been obtained, these parameters being independent of the initial H2SO4 concentration. The character of peripheral functional substituents in H2P has been shown to be responsible for the stability of the studied oxo complexes to chemical oxidation in aerated acids.

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References

  1. A. B. P. Lever, E. R. Milaeva, and G. Speier, Phthalocyanines: Properties and Applications, Ed. by C. C. Leznoff and A. B. P. N. Lever (VCH, New York, 1993), Vol. 3.

    Google Scholar 

  2. E. A. Batanova, S. A. Borisenkova, O. V. Dolotova, and O. L. Kaliya, Vestn. Mosk. Univ., Ser. Khim. 41, 123 (2000).

    CAS  Google Scholar 

  3. M. Toganoh, S. Ikeda, and H. Furuta, Inorg. Chem. 46, 10003 (2007).

    Article  CAS  Google Scholar 

  4. J. P. Collman, J. M. Garner, and L. K. Woo, J. Am. Chem. Soc. 111, 8141 (1989).

    Article  CAS  Google Scholar 

  5. J. P. Collman and H. J. Arnold, Acc. Chem. Res. 26, 586 (1993).

    Article  CAS  Google Scholar 

  6. K. E. Splan, M. H. Keefe, A. M. Massari, et al., Inorg. Chem. 41, 619 (2002).

    Article  CAS  Google Scholar 

  7. J. W. Buchler, A. Cian, J. Fischer, et al., Chem. Bericht. 123, 2247 (2006).

    Article  Google Scholar 

  8. M. Toganoh, S. Ikeda, and H. Furuta, Chem. Commun., 4589 (2005).

    Google Scholar 

  9. M. Toganoh, K. Fujino, S. Ikeda, and H. Furuta, Tetrahedron Lett. 49, 1488 (2008).

    Article  CAS  Google Scholar 

  10. A. Ghosh and M. Ravikanth, Inorg. Chem. 51, 6700 (2012).

    Article  CAS  Google Scholar 

  11. E. Yu. Tyulyaeva, N. G. Bichan, T. N. Lomova, and E. G. Mozhzhukhina, Russ. J. Inorg. Chem. 57, 1295 (2012).

    Article  CAS  Google Scholar 

  12. E. Yu. Tyulyaeva, N. G. Bichan, and T. N. Lomova, Russ. J. Inorg. Chem. 58, 1366 (2013).

    Article  CAS  Google Scholar 

  13. N. G. Bichan, E. Yu. Tyulyaeva, and T. N. Lomova, Russ. J. Inorg. Chem. 59, 1445 (2014).

    Article  CAS  Google Scholar 

  14. N. G. Bichan, E. Yu. Tyulyaeva, T. N. Lomova, Russ. J. Phys. Chem. A 88, 1719 (2014).

    Article  CAS  Google Scholar 

  15. T. V. Lubimova, S. A. Syrbu, and A. S. Semeikin, Macroheterocycles 9, 59 (2016).

    Article  Google Scholar 

  16. N. G. Bichan, E. Yu. Tyulyaeva, T. N. Lomova, and A. S. Semeikin, Russ. J. Org. Chem. 50, 1361 (2014).

    Article  CAS  Google Scholar 

  17. T. N. Lomova and B. D. Berezin, Koord. Khim. 27, 96 (2001).

    Article  Google Scholar 

  18. E. Stulz, S. M. Scott, A. D. Bond, et al., Inorg. Chem. 42, 3086 (2003).

    Article  CAS  Google Scholar 

  19. K. S. Chan and Ch. M. Lau, Organometallics 25, 260 (2006).

    Article  CAS  Google Scholar 

  20. J. W. Buchler and S. B. Kruppa, Z. Naturforsch. B 45, 518 (1990).

    CAS  Google Scholar 

  21. N. G. Bichan, E. Yu. Tyulyaeva, I. A. Khodov, and T. N. Lomova, J. Mol. Struct. 1061, 82 (2014).

    Article  CAS  Google Scholar 

  22. Industrial Fluororganic Products. Handbook, Ed. by I. I. Krylov (Leningrad, 1990), p. 367 [in Russian].

  23. Yu. Yu. Lur’e, The Analytical Chemistry Handbook (Khimiya, Moscow, 1967) [in Russian].

    Google Scholar 

  24. U. A. Spitzer, T. W. Toone, and R. Stewart, Can. J. Chem. 54, 440 (1976).

    Article  CAS  Google Scholar 

  25. J. P. Collman, P. C. Herrmann, L. Fu, et al., J. Am. Chem. Soc. 119, 3481 (1997).

    Article  CAS  Google Scholar 

  26. J. A. Bailey, J. Chem. Ed. 88, 995 (2011).

    Article  CAS  Google Scholar 

  27. L. LC. Olijvea, E. N. W. Howa, M. Bhadbhadeb, et al., J. Porphyrins Phthalocyanines 15, 1345 (2011).

    Article  Google Scholar 

  28. D. H. McDaniel and H. C. Brown, Org. Chem. 23, 420 (1958).

    Article  CAS  Google Scholar 

  29. K. M. Kadish and M. M. Morrison, J. Am. Chem. Soc. 98, 3326 (1976).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, 153045, Russia

    E. Yu. Tyulyaeva, N. G. Bichan & T. N. Lomova

  2. Ivanovo State University of Chemical Technology, Ivanovo, 153000, Russia

    A. S. Semeikin

Authors
  1. E. Yu. Tyulyaeva
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  2. N. G. Bichan
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  3. T. N. Lomova
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  4. A. S. Semeikin
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Corresponding author

Correspondence to T. N. Lomova.

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Original Russian Text © E.Yu. Tyulyaeva, N.G. Bichan, T.N. Lomova, A.S. Semeikin, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 12, pp. 1585–1592.

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Tyulyaeva, E.Y., Bichan, N.G., Lomova, T.N. et al. 5,15-bis(4′-methoxyphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphin axial complexes of rhenium: Synthesis and reactions in protic solvents. Russ. J. Inorg. Chem. 62, 1576–1583 (2017). https://doi.org/10.1134/S0036023617120208

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  • DOI: https://doi.org/10.1134/S0036023617120208

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