Skip to main content
SpringerLink
Log in

Tris(3-fluorophenyl)antimony dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = CH2Cl, Ph, CH2C6H4NO2-4, C10H15): Synthesis and structure

  • Coordination Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Tris(3-fluorophenyl)antimony dicarboxylates (3-FC6H4)3Sb[OC(O)R]2, R = CH2Cl (I), Ph (II), CH2C6H4NO2-4 (III), C10H15 (IV)) have been synthesized with a high yield by the reaction between tris(3-fluorophenyl)antimony and carboxylic acids in ether in the presence of tert-butyl hydroperoxide. The Sb atoms in complexes I–IV have a distorted trigonal bipyramidal coordination with carboxylate ligands in axial positions. The OSbO angles are 176.61(11)° (I), 177.8(2)°, 175.9(3)° (II), 173.25(16)° (III), and 177.84(14)° (IV). The Sb–O and Sb–Ceqv bond lengths are 2.111(3), 2.131(3) and 2.102(5)–2.117(4) Å (I); 2.101(1)–2.547(6) and 2.103(8)–2.132(7) Å (II); 2.035(7), 2.144(6) and 2.116(9)–2.130(10) Å (III); 2.131(5), 2.156(4) and 2.103(2)–2.153(5) Å (IV). The carboxylate ligands show anisobidentate properties, and the Sb⋯О=С distances are 2.804(4), 2.923(4) Å (I), 2.541(8)–2.747(9) Å (II), 2.967(9), 3.007(9) Å (III), and 2.561(9), 2.617(9) Å (IV). The structural organization in crystals is based on weak intermolecular hydrogen bonds H⋯F (2.48–2.64 Å) and H⋯O(=C) (2.55–2.71 Å).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. R. T. Tiekink, Crit. Rev. Oncol./Hematol 42, 217 (2002).

    Article  Google Scholar 

  2. I. I. Ozturk, C. N. Banti, M. J. Manos, et al., J. Inorg. Biochem. 109, 57 (2012).

    Article  CAS  Google Scholar 

  3. M. I. Ali, M. K. Rauf, A. Badshah, et al., Dalton Trans. 42, 16733 (2013).

    Article  CAS  Google Scholar 

  4. Cambridge Crystallographic Data Center. 2015 (deposit@ccdc.cam.ac.uk; http://www.ccdc.cam.ac.uk).

  5. L. Yu, Y.-Q. Ma, G.-C. Wang, and J.-Sh. Li, Heteroat. Chem. 15, 32 (2004).

    Article  CAS  Google Scholar 

  6. L. Yu and Y.-Q. Ma, Run-Ch. Liu, et al., Polyhedron 23, 823 (2004).

    Article  CAS  Google Scholar 

  7. V. V. Sharutin, O. K. Sharutina, and A. N. Yadryshnikov, Butlerovskie Soobshch. 39, 127 (2014).

    Google Scholar 

  8. SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System (Bruker, Madison, Wisconsin, USA, 1998).

    Google Scholar 

  9. SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data (Bruker, Madison, Wisconsin, USA (1998).

    Google Scholar 

  10. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr. 42, 339 (2009).

    Article  CAS  Google Scholar 

  11. O. K. Sharutina and V. V. Sharutin, Molecular Structures of Organic Antimony(V) Compounds (YuUrGU Press, Chelyabinsk, 2012) [in Russian].

    Google Scholar 

  12. V. V. Sharutin, O. K. Sharutina, A. P. Pakusina, et al., Koord. Khim. 29, 843 (2003).

    Google Scholar 

  13. V. V. Sharutin, B. C. Senchurin, O. K. Sharutina, and O. V. Chagarova, Vestn. YuUrGU, Ser. Khim., No. 6, 47 (2011).

    Google Scholar 

  14. V. V. Sharutin, V. S. Senchurin, O. K. Sharutina, et al., Zh. Obshch. Khim. 79, 1636 (2009).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National South Ural State Research University, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina, R. V. Reshetnikova, E. V. Lobanova & A. N. Efremov

Authors
  1. V. V. Sharutin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. K. Sharutina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. V. Reshetnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. V. Lobanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. N. Efremov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Sharutin.

Additional information

Original Russian Text © V.V. Sharutin, O.K. Sharutina, R.V. Reshetnikova, E.V. Lobanova, A.N. Efremov, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 11, pp. 1457–1463.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sharutin, V.V., Sharutina, O.K., Reshetnikova, R.V. et al. Tris(3-fluorophenyl)antimony dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = CH2Cl, Ph, CH2C6H4NO2-4, C10H15): Synthesis and structure. Russ. J. Inorg. Chem. 62, 1450–1457 (2017). https://doi.org/10.1134/S003602361711016X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S003602361711016X

Search

Navigation