Skip to main content
SpringerLink
Log in

Ion-selective properties of 1,2-bis[2-(2-diphenylphosphorylmethylphenoxy)ethoxy]benzene (L1) and 1,2-bis[2-(2-diphenylphosphorylphenoxy)ethoxy]benzene (L2). Crystal structure of complexes [CdI2(μ-L1)]2, [CdBr2 (μ-L1)]2 · C2H5OH, and [Cd(L2)2(H2O)2][Cd2I6]

  • Coordination Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Ion-selective properties of polymeric plasticized membranes of ion-selective electrodes based on 1,2-bis[2-(2-diphenylphosphorylmethylphenoxy)ethoxy]benzene (L1) and 1,2-bis[2-(2-diphenylphosphorylphenoxy)ethoxy]benzene (L2) toward certain bivalent metal cations has been studied. It has been shown that podand L2 can be used as a sensor component of polymeric plasticized membrane of ion-selective electrode for quantitative determination of Pb2+ ions in aqueous solutions. The structure of complexes [CdI2(μ-L1)]2, [Cd(μ-L1)Br2]2 · C2H5OH, and [Cd(L2)2(H2O)2][Cd2I6] has been studied by X-ray diffraction and IR spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. O. M. Petrukhin, E. V. Shipulo, S. A. Krylova, et al., Zh. Anal. Khim. 49, 1299 (1994).

    CAS  Google Scholar 

  2. M. Yu. Nemilova, N. V. Shvedene, V. L. Filimonova, et al., Zh. Anal. Khim. 49, 418 (1994).

    Google Scholar 

  3. N. V. Shvedene, T. V. Shishkanova, V. E. Baulin, et al., Vestn. Mosk. Univ., Ser. 2: Khim. 37, 273 (1996).

    CAS  Google Scholar 

  4. O. M. Petrukhin, S. N. Kurachenkova, E. A. Sonina, et al., J. Anal. Chem. 57, 313 (2002).

    Article  Google Scholar 

  5. E. S. Krivorot’ko, I. N. Polyakova, I. S. Ivanova, et al., Russ. J. Inorg. Chem. 61, 1241 (2016). doi 10.1134/S0036023616100132

    Article  Google Scholar 

  6. N. I. Movchan, N. N. Umarova, R. A. Yusupov, et al., RF Patent No. 2152609 (1999).

    Google Scholar 

  7. E. N. Pyatova, A. N. Kopytin, E. G. Il’in, et al., RF Patent No. 2054666 (1996).

    Google Scholar 

  8. D. O. Kirsanov, A. V. Legin, V. A. Babain, et al., RF Patent No. 2315988 (2006).

    Google Scholar 

  9. E. N. Pyatova, I. N. Polyakova, I. S. Ivanova, et al., Russ. J. Inorg. Chem. 62, 431 (2017).

    Article  CAS  Google Scholar 

  10. L. Kh. Minacheva, I. S. Ivanova, I. K. Kireeva, et al., Zh. Neorg. Khim. 39, 1143 (1994).

    Google Scholar 

  11. L. Kh. Minacheva, I. S. Ivanova, I. K. Kireeva, et al., Crystallogr. Rep. 45, 52 (2000).

    Article  Google Scholar 

  12. I. S. Ivanova, I. N. Polyakova, V. E. Baulin, et al., Russ. J. Gen. Chem 86, 865 (2016). doi 10.1134/S1070363216040186

    Article  Google Scholar 

  13. V. E. Baulin, I. S. Ivanova, I. N. Polyakova, et al., Russ. J. Gen. Chem. 85, 899 (2015). doi 10.1134/S1070363215040234

    Article  CAS  Google Scholar 

  14. APEX2, SAINT, SADABS (Bruker AXS Inc., Madison, Wisconsin, 2008–2009).

  15. G. M. Sheldrick, Acta Crystallogr. 64, 112 (2008).

    Article  CAS  Google Scholar 

  16. L. Palatinus and G. Chapius, J. Appl. Crystallogr. 40, 786 (2007).

    Article  CAS  Google Scholar 

  17. L. Palatinus, S. J. Prathapa, and S. van Smaalen, J. Appl. Crystallogr. 45, 575 (2012).

    Article  CAS  Google Scholar 

  18. IUPAC. Recommendation for Nomenclature of Ion Selective Electrodes, Pure Appl. Chem. 48, 127 (1976).

  19. E. Bakker, E. Pretsch, and P. Buhlmann, Anal. Chem. 72, 1127 (2000).

    Article  CAS  Google Scholar 

  20. R. C. Hayward, C. H. Overton, and G. H. Whitham, J. Chem. Soc., Perkin Trans. 1, 2413 (1976).

    Article  Google Scholar 

  21. X.-J. Yang, X. Liu, Y. Liu, et al., Polyhedron 29, 934 (2010).

    Article  CAS  Google Scholar 

  22. K. Sreevani, K. Thangaraj, K. Ramamurthi, et al., J. Cryst. Growth 322, 78 (2011).

    Article  CAS  Google Scholar 

  23. I. A. Zamilatskov, E. V. Savinkina, and D. V. Al’bov, Russ. J. Coord. Chem. 33, 396 (2007).

    Article  CAS  Google Scholar 

  24. E. V. Savinkina, I. A. Zamilatskov, E. A. Buravlev, and D. V. Albov, Mendeleev Commun. 18, 131 (2008).

    Article  CAS  Google Scholar 

  25. C. C. Hines, W. M. Reichert, S. T. Griffin, et al., J. Mol. Struct. 796, 76 (2006).

    Article  CAS  Google Scholar 

  26. G.-Ch. Xu, Y.-J. Ding, T. Okuamura, et al., Cryst. Eng. Comm. 10, 1052 (2008).

    Article  CAS  Google Scholar 

  27. R. L. Oriolli and M. Clampolini, Chem. Commun. 1280 (1972).

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    I.S. Ivanova, I.N. Polyakova & E.N. Pyatova

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    I.S. Ivanova, E.S. Krivorot’ko, E.N. Pyatova, V.E. Baulin & A.Yu. Tsivadze

  3. Institute of Physiologically Active Substances, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V.E. Baulin

Authors
  1. I.S. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I.N. Polyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E.S. Krivorot’ko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E.N. Pyatova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V.E. Baulin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A.Yu. Tsivadze
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I.S. Ivanova.

Additional information

Original Russian Text © I.S. Ivanova, I.N. Polyakova, E.S. Krivorot’ko, E.N. Pyatova, V.E. Baulin, A.Yu. Tsivadze, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 10, pp. 1308–1316.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ivanova, I., Polyakova, I., Krivorot’ko, E. et al. Ion-selective properties of 1,2-bis[2-(2-diphenylphosphorylmethylphenoxy)ethoxy]benzene (L1) and 1,2-bis[2-(2-diphenylphosphorylphenoxy)ethoxy]benzene (L2). Crystal structure of complexes [CdI2(μ-L1)]2, [CdBr2 (μ-L1)]2 · C2H5OH, and [Cd(L2)2(H2O)2][Cd2I6]. Russ. J. Inorg. Chem. 62, 1299–1307 (2017). https://doi.org/10.1134/S0036023617100102

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023617100102

Search

Navigation