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Bismuth complexes [p-Tol4P] +2 [Bi2I8(THF)2]2–, [p-Tol4Sb] +2 [Bi2I8(THF)2]2–, [p-Tol4P] +2 [Bi2I8(DMSO)2]2–, [Bu4P] + n [(Bi2I7) n ]n–, [p-Tol4P] + n [(Bi2I7) n ]n–, and [p-Tol4Sb] + n [(Bi2I7) n ]n–: Synthesis and structure

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Abstract

The complexes [p-Tol4P] +2 [Bi2I8(THF)2]2–, [p-Tol4Sb] +2 [Bi2I8(THF)2]2–, [p-Tol4P] +2 [Bi2I8(DMSO)2]2–, [Bu4P] + n [(Bi2I7) n ]n–, [p-Tol4P] n +[(Bi2I7) n ]n–, and [p-Tol4Sb] + n [(Bi2I7) n ]n– were synthesized by the reaction between bismuth iodides and tetrabutyl- and tetraphenylphosphonium, tetra-para-tolylphosphonium and -stibonium iodides in tetrahydrofuran, dimethyl sulfoxide, acetone, and ethyl cellosolve. The crystal structures of the synthesized complexes containing bi- and polynuclear anions with an octahedral coordination of bismuth atoms were characterized by X-ray diffraction.

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Authors and Affiliations

  1. National South Ural State Research University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina, R. M. Khisamov & V. S. Senchurin

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. R. M. Khisamov
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  4. V. S. Senchurin
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, R.M. Khisamov, V.S. Senchurin, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 6, pp. 782–793.

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Sharutin, V.V., Sharutina, O.K., Khisamov, R.M. et al. Bismuth complexes [p-Tol4P] +2 [Bi2I8(THF)2]2–, [p-Tol4Sb] +2 [Bi2I8(THF)2]2–, [p-Tol4P] +2 [Bi2I8(DMSO)2]2–, [Bu4P] + n [(Bi2I7) n ]n–, [p-Tol4P] + n [(Bi2I7) n ]n–, and [p-Tol4Sb] + n [(Bi2I7) n ]n–: Synthesis and structure. Russ. J. Inorg. Chem. 62, 766–776 (2017). https://doi.org/10.1134/S0036023617060201

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