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Extension rules

  • Physicochemical Analysis of Inorganic Systems
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Abstract

The statement that the solubility is higher for metastable phases than for stable phases can be proved by a relatively simple imaginary experiment. Hence, it follows that the metastable extensions of the solubility limit curves, surfaces, and hypersurfaces in the phase diagrams of binary, ternary, and multicomponent systems cannot run in the single-phase solvent region. A special case for binary systems is the Hollmann’s rule.

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Authors and Affiliations

  1. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow, 119991, Russia

    P. P. Fedorov

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  1. P. P. Fedorov
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Correspondence to P. P. Fedorov.

Additional information

This paper was reported at the 11th International Kurnakov Meeting on Physicochemical Analysis (Voronezh, June 27–July 1, 2016).

Original Russian Text © P.P. Fedorov, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 5, pp. 559–563.

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Fedorov, P.P. Extension rules. Russ. J. Inorg. Chem. 62, 558–562 (2017). https://doi.org/10.1134/S0036023617050114

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  • DOI: https://doi.org/10.1134/S0036023617050114

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